A reaction mechanism is proposed for tritium labelling by the SCRD method /solid-state catalytic reductive dehalogenation/ based on hydrogen spillover. A model system /palladium membrane with a layer of the original organic compound/ is used for a kinetic study of the debromination of 5-bromouracil and the isotope exchange of α-alanine at pressure of 0.07–20 kPa. A kinetic model is considered for the spillover stoppage due to the contamination of penetration centres by the reaction product. Other possible causes of the spillover stoppage are discussed.
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N. F. Myasoedov, N. S. Marchenkov, K. S. Mikhailov, “Organicheskie soedinenija mechenye radioaktivnymi izotopami”, Proc. Intern. Symp., Marinske Lazne, May 1976, CZKAE Praha 1977, p. 275–283.
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A. V. Filikov, N. F. Myasoedov,Izv. Akad. Nauk USSR, ser. Khim. /in print/.
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Filikov, A.V., Myasoedov, N.F. A study of tritium labelling by solid-state catalytic reductive dehalogenation. Journal of Radioanalytical and Nuclear Chemistry Letters 85, 373–380 (1984). https://doi.org/10.1007/BF02164061
- Physical Chemistry
- Inorganic Chemistry
- Organic Compound