Experientia

, Volume 20, Issue 3, pp 128–129 | Cite as

The oxidation of N-2-Fluorenamine and 4-Aminobiphenyl by peracetic acid

  • H. R. Gutmann
Kurze Mitteilungen

Keywords

Oxidation Peracetic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Zusammenfassung

Im Gegensatz zu neueren Befunden von anderen Autoren finden wir, dass die Oxydation von 2-Fluorenamin oder 4-Aminodiphenyl mit Peressigsäure keine Nitrosoderivate bildet, sondern die Azoverbindungen 2,2′-Azoxybisfluoren und 4,4′-Azobisdiphenyl.p-Nitroanilin wird zu einem Gemisch oxydiert, aus dem manp, p-Dinitroazoxybenzol undp, p′-Dinitroazobenzol durch Chromatographie an Kieselgel isolieren kann.

References

  1. 2.
    H. Uehleke, Exper.17, 557 (1961).Google Scholar
  2. 3.
    H. Uehleke, Biochem. Pharmacol.12, 213 (1963).Google Scholar
  3. 4.
    R. R. Holmes andR. P. Bayer, J. Amer. chem. Soc.82, 3454 (1960).Google Scholar
  4. 5.
    J. Zimmermann, Ber. dtsch. chem. Ges.13, 1960 (1880).Google Scholar
  5. 6.
    F. E. Cislak, I. M. Eastman, andJ. K. Senior, J. Amer. chem. Soc.49, 2318 (1927).Google Scholar
  6. 8.
    O. N. Witt andE. Kopetschni, Ber. dtsch. chem. Ges.45, 1134 (1912) andA. H. Cook andD. G. Jones, J. chem. Soc.1939, 1309 reported melting points of 220–221° and 214–216°, respectively, forp, p′-dinitroazobenzene prepared by persulfate oxidation ofp-nitroaniline. No elementary analyses are available for these products and they were probably mixtures, since according toWitt andKopetschni p, p′-dinitroazobenzene andp, p′-dinitroazooxybenzene form mixed crystals.Google Scholar
  7. 9.
    A. Werner andE. Stiasny, Ber. dtsch. chem. Ges.32, 3258 (1899).Google Scholar

Copyright information

© Birkhäuser Verlag 1964

Authors and Affiliations

  • H. R. Gutmann
    • 1
    • 2
  1. 1.Cancer Research LaboratoryVeterans Administration HospitalMinneapolis
  2. 2.Department of BiochemistryUniversity of MinnesotaMinneapolisUSA

Personalised recommendations