Journal of thermal analysis

, Volume 46, Issue 2, pp 347–352 | Cite as

Interpolymer complexes of a new type

Three-component interpolymer complexes involving a monobasic low molar mass mediator
  • N. V. Avramenko
  • O. V. Kargina
  • O. V. Prazdnichnaya
  • M. N. Phrolov
  • I. D. Jurgens
  • S. L. Davidova
13th IUPAC Conference on Chemical Thermodynamics

Abstract

A new type of three-component interpolymer complexes (3IPCM) formed by two similarly charged polyelectrolytes and an oppositely charged low molar mass compound was studied by DSC, NMR and X-ray methods. The low molar mass monobasic compounds in these complexes act as mediators. This type of complexes differs from earlier-obtained 3IPCM, which contained a dibasic low molar mass mediator.

The present 3IPCM were obtained from two polymers (polyacrylic acid and sodium polyphosphate) and bases such as 4-vinylpyridine and 2-methyl-5-vinylpyridine.

Keywords

DSC optical densities thermal stability three-component interpolymer complexes 

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Copyright information

© Akadémiai Kiadó 1996

Authors and Affiliations

  • N. V. Avramenko
    • 1
  • O. V. Kargina
    • 2
  • O. V. Prazdnichnaya
    • 2
  • M. N. Phrolov
    • 1
  • I. D. Jurgens
    • 2
  • S. L. Davidova
    • 2
  1. 1.Department of ChemistryMoscow State UniversityMoscowRussia
  2. 2.Topchiev Institute of Petrochemical Synthesis of RASMoscowRussia

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