Propylene effect on propane dehydrogenation in oxidative ammonolysis
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Abstract
Effect of propylene on the step of propane dehydrogenation to propylene in oxidative ammonolysis of propane to acrylonitrile has been studied. It is shown that in this reaction, besides catalytic propylene formation, a non-catalytic process also takes place. The autocatalytic formation of C3H6 is observed, which can be due to the degenerated branched chain production of propylene.
Keywords
Physical Chemistry Catalysis Propylene Dehydrogenation C3H6Abstract
Исследовано влияние пропилена на стадию дегидрирования пропана в пропилен в реакции окислительного аммонолиза пропана в акрилонитрил. Показано, что в этой реакции наряду с каталитическим происходит некаталитическое образование пропилена, причем наблюдается автокатализ образования C3H6, что может быть обусловлено цепным вырожденно-разветвленным процессом образования пропилена.
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