Reaction Kinetics and Catalysis Letters

, Volume 55, Issue 2, pp 365–372 | Cite as

Studies on the conversion of isopentane over shape selective zeolites, I. H-ZSM-5 and H-ZSM-11 zeolites

  • Oscar A. Anunziata
  • Liliana B. Pierella
Article

Abstract

H-ZSM-5 and H-ZSM-11 efficiently catalyze the conversion of isopentane into aromatic hydrocarbons.n-Pentane produces more aromatic hydrocarbons than isopentane, but at low conversion levels (high space velocity) isopentane was about two times more reactive thann-pentane in terms of the first order rate constant for the cracking of the pentane isomers.

Keywords

Physical Chemistry Zeolite Catalysis Hydrocarbon Aromatic Hydrocarbon 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    N. Y. Chen, T. Y. Yan:Ind. Eng. Chem. Process Des. Dev.,25, 151 (1986).Google Scholar
  2. 2.
    T. Mole, J. R. Anderson, G. Creer:Appl. Catal.,17, 141 (1985).Google Scholar
  3. 3.
    Y. Ono:Catal. Rev.-Sci. Eng.,34, 179 (1992).Google Scholar
  4. 4.
    Y. Ono, H. Kitagawa, Y. Sendoda:J. Chem. Soc. Faraday Trans. I,83, 2913 (1987).Google Scholar
  5. 5.
    E. A. Lombardo, W. H. Hall:J. Catal.,112, 565 (1988).Google Scholar
  6. 6.
    G. Giannetto, S. Sausare, M Guisnet:J. Chem. Soc. Chem. Commun., 1302 (1986).Google Scholar
  7. 7.
    N. Y. Chen, W. E. Garwood:J. Catal.,52, 52 (1978).Google Scholar
  8. 8.
    C. Mirodatos, A. Biloul, D. Barthomeuf:J. Chem. Soc., Chem. Commun., 149 (1987).Google Scholar
  9. 9.
    W. O. Haag, R. M. Lago, P. B. Weisz:Faraday Discuss,72, 317 (1981).Google Scholar
  10. 10.
    E. A. Lombardo, T. R. Gaffney, W. K. Hall: 9th Int. Congress on Catalysis, Calgary, Canada; 412, 1988.Google Scholar
  11. 11.
    O. A. Anunziata, O. A. Orio, E. R. Herrero, A. F. Lopez, C. F. Perez, A. R. Suarez:Appl. Catal.,15, 235 (1985).Google Scholar
  12. 12.
    L. B. Pierella, O. A. Anunziata, O. A. Orio, M. V. Cortes: XII Iberoamerican Simposium of Catalysis, Brazil 1990.Google Scholar
  13. 13.
    J. N. Miale, Y. N. Chen, P. B. Weisz:J. Catal.,6, 278 (1966).Google Scholar
  14. 14.
    L. B. Pierella, O. A. Anunziata:Lat. Am. Appl. Res., 1994. in press.Google Scholar
  15. 15.
    O. A. Anunziata, O. A. Orio, M. C. Aguirre, L. B. Pierella:React. Kinet. Catal. Lett.,37, 205 (1988).Google Scholar
  16. 16.
    O. A. Anunziata, L. B. Pierella:React. Kinet. Catal. Lett.,49, 311 (1993).Google Scholar
  17. 17.
    Y. Zhao, G. R. Bamwenda, B. W. Wojciechowski:J. Catal.,142, 465 (1993).Google Scholar

Copyright information

© Akadémiai Kiadó 1995

Authors and Affiliations

  • Oscar A. Anunziata
    • 1
  • Liliana B. Pierella
    • 1
  1. 1.Facultad Regional CórdobaCentro de Investigaciones Tecnológicas-GRUCOM Universidad Tecnológica NacionalCórdobaRepública Argentina

Personalised recommendations