Oxidation of 2-ethylhexanal in the liquid phase
II. Catalytic pathway
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Abstract
The oxidation of 2-ethylhexanal with oxygen in the liquid phase in the presence of transition metal soaps (containing Mn, Co, Fe, Cu, Ni and Cr) as catalysts has been studied at 313.2 K. Similarly as in the liquid phase, 2-ethylhexanoic acid (maximum yield 79.6% at 80.8% selectivity) was the main reaction product. As side — products 3-heptyl formate, 3-heptanol, 3-heptanone, and heptane were identified.
Keywords
Oxidation Oxygen Physical Chemistry Catalysis Liquid Phase
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References
- 1.S. Miyazaki, Y. Suhara:J. Am. Oil. Chem. Soc. 55, 536 (1978).Google Scholar
- 2.W. Ando, I. Nakaoka:Ger. Offen. DE 2826065, 11 January, 1979.Google Scholar
- 3.A. Kimura, B. Miya:Jpn. Kokai Tokkyo Koho, JP 53135919, 28 November, 1978.Google Scholar
- 4.N.N. Tsekhina, B.G. Freidin, I.G. Uryukina:Neftekhimiya,24, 63 (1984).Google Scholar
- 5.I.V. Rudik, I.A. Avrutskaya:Zh. Prikl. Khim. (Leningrad),61, 1334 (1988).Google Scholar
- 6.J. Kaulen, H.J. Schaefer:Tetrahedron,38, 3299 (1982).Google Scholar
- 7.I. Oprescu, I. Stanciu, M. Ramneamtu et al.: RO 87-127123, 23 February, 1987; CA 113 (23): 211379v.Google Scholar
- 8.T. Maki:Jpn. Kokai Tokkyo Koho, JP 54009203, 24 January 1979.Google Scholar
- 9.B. Cornils, W. Dewin, J. Weber:Ger. Offen, DE 2931154, 26 February, 1981.Google Scholar
- 10.T. Maki:Jpn. Kokai Tokkyo Koho, JP 53105412, 13 September, 1978.Google Scholar
- 11.T. Maki:Jpn. Kokai Tokkyo Koho, JP 53105413, 13 September, 1978.Google Scholar
- 12.M. Gliński, J. Kijeński:React. Kinet. Catal. Lett.,55, 311 (1995).Google Scholar
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© Akadémiai Kiadó 1995