Acetylacetonate of indium: Structure and reactivity with 1,3-dienes
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Abstract
The reaction of isoprene and 2,3-dimethyl-1,3-butadiene with indium tris-acetylacetonate, afforded C- and O-al-kylation products together with an oligomeric mass. A mechanism of diene transformation is proposed in which π-diene-metal species could be involved.
Keywords
Indium Physical Chemistry Catalysis Diene Isoprene
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Abstract
Реакция изопрена и 2,3-диметил-1,3-бутадиена с трисацетилацетонатом индия дает продукты С− и О-алкилирования вместе с олигомерной массой. Предложен механизм превращения диенов, который включает в себя частицы Пдиен--металл.
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© Akadémiai Kiadó 1988