Ru(III) catalyzed oxidation of acetanilide and substituted acetanilides by potassium iodate in aqueous acetic acid medium at constant ionic strength
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Abstract
The order with respect to [Ru(III)] is unity while zero order with respect to [IO3−] and complex dependence on [substrate] have been observed. The variation of [HClO4] and solvent composition have no pronounced effect on the rate. A plausible mechanism is suggested.
Keywords
Oxidation Acetic Potassium Physical Chemistry Acetic Acid
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Abstract
Заглавная реакция имеет первый пор〚ок по отношению [Ru(III)], нулевой порядок по отношению [IO3−] и имеет сложную зависимость от концентрации субстрата. Изменение концентрации CClO4 и состава растворителей не оказывает заметного зффекта на скорость реакции. Предлагается вероятный механизм протекания реакции.
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References
- 1.M. D. Prasada Rao, J. Padmanabha: Indian J. Chem.,20-A, 133 (1983).Google Scholar
- 2.J. Horiuchi, O. Tchijyo: C. A.72, 50624 (1970).Google Scholar
- 3.J. Hine: Physical Organic Chemistry, p. 176. McGraw Hill, New York.Google Scholar
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© Akadémiai Kiadó 1984