Investigation of propylene oxidation on multicomponent a Bi-and Mo-based oxide catalyst
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Abstract
It has been established that porpylene oxidation to acrolein on a multicomponent oxide catalyst containing Mo, Bi, Fe, Ni, Co, K, P and SiO2 follows an alternating oxidation-reduction mechanism and involves the participation of lattice oxygen with the bond energy of about 280 kJ/mol.
Keywords
Oxidation Oxygen Physical Chemistry SiO2 Catalysis
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Abstract
Окисление пропилена в акролеин на многокомпонентном оксидном катализаторе, включающем Mo, Bi, Fe, Ni, Co, K, P и SiO2 протекает по механизму попеременного окислениявосстановления с участием решеточного кислорода с энергией связи около 280 кДж/моль.
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References
- 1.G.K. Boreskov: Kinet. Katal.,14, 7 (1970).Google Scholar
- 2.G.K. Boreskov, S.A. Veniaminov, N.N. Sazonova, Yu.D. Pankratiev, A.N. Pitayeva: Kinet. Katal.,16, 1442 (1975).Google Scholar
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© Akadémiai Kiadó 1985