Reaction Kinetics and Catalysis Letters

, Volume 32, Issue 2, pp 313–318 | Cite as

Gas phase thermolysis of diisopropyl disulfide

  • G. Martin
Article
Received:

Abstract

The pyrolysis of diisopropyl disulfide was studied in a static system over the temperature range 274–304 °C at subambient pressures. The mechanism was examined by the pyrolysis of 3,4-dithia-2,5-dideuterohexane. The inhibited rate of consumption yielded the Arrhenius parameters logA=14.37±0.36; Ea=(192±4) kJ/mol.

Keywords

Physical Chemistry Catalysis Pyrolysis Disulfide Static System 
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Abstract

Пиролиз диизопропилдисульфида исследован в статической системе в интервале температур 274–304°C в вакууме. Механизм проверяли пиролизом 3,4-дитиа-2,5-дидейтерогексана. Ингибированная скорость расхода приводит к следующим аррениусовским параметрам: logA=14,37±0,36; Ea=(192±4) кДж/моль.

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Copyright information

© Akadémiai Kiadó 1986

Authors and Affiliations

  • G. Martin
    • 1
  1. 1.I. V. I. C.Centro de QuimicaCaracasVenezuela

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