Reaction Kinetics and Catalysis Letters

, Volume 26, Issue 3–4, pp 317–322 | Cite as

Kinetic studies of catalytic epoxidation of Si-containing olefins by tert-butylhydroperoxide

  • I. A. Gailyunas
  • E. M. Tsyrlina
  • G. A. Tolstikov
  • S. I. Spivak
  • V. D. Komissarov
Article
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Abstract

Kinetics and products of the epoxidation of several substituted sila-cyclo-3-pentenes by tert-butylhydroperoxide (ROOH) in the presence of Mo(CO)6 at 70°C in chlorobenzene have been studied and an epoxidation mechanism is suggested. Effective rate constants have beeb shown to be practically independent of the structure of olefins examined.

Keywords

Physical Chemistry Catalysis Epoxidation Kinetic Study Effective Rate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Изучена кинетика, продукты и предложен механизм зпоксидирования ряда замеъенных силацикло-3-пентенов (I–VI-) трет. бутилгидропероксидом (ROOH) в присутствии Mo(CO)6 при 70°C в растворе хлорбензола. Определены зффективные константы скорости реакции, которые фактически не зави⇒ят от строения изученных олефинов.

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Copyright information

© Akadémiai Kiadó 1984

Authors and Affiliations

  • I. A. Gailyunas
    • 1
  • E. M. Tsyrlina
    • 1
  • G. A. Tolstikov
    • 1
  • S. I. Spivak
    • 1
  • V. D. Komissarov
    • 1
  1. 1.Institute of ChemistryUfaUSSR

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