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Reaction Kinetics and Catalysis Letters

, Volume 17, Issue 3–4, pp 379–383 | Cite as

Character of hydrocarbon activation and catalytic activity of solid catalysts in deep oxidation reactions

  • V. D. Sokolovskii
Article
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Abstract

In terms of a single conception, the relative reactivity of hydrocarbons and the activity of solid catalysts in reactions of deep oxidation are interpreted for the ITi type mechanism. It is shown that for the oxidation of saturated hydrocarbons the most important is the acceptor interaction of hydrocarbons with catalysts, whereas for the oxidation of unsaturated compounds, of significance are both the donor and acceptor interactions.

Keywords

Oxidation Physical Chemistry Catalysis Hydrocarbon Catalytic Activity 

Abstract

В рамках единого подхода дана трактовка относительной реакционной способности углеводородов и активности твёрдых катализаторов в реакциях глубокого окисления для механизмов типа НПВ. Показано, что при окислении насьщенных углеводородов наиболее важным является акцепторное взаимодействие углеводорода с катализатором, при окислении насыщенных соединений существенно как донорное, так и акцепторное взаимодействие.

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Copyright information

© Akadémiai Kiadó 1981

Authors and Affiliations

  • V. D. Sokolovskii
    • 1
  1. 1.Institute of CatalysisNovosibirskUSSR

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