Determination of trace elements in Egyptian cane sugar by neutron activation analysis

  • R. M. Awadallah
  • M. K. Sherif
  • A. E. Mohamed
  • F. Grass
Article

Abstract

Major, minor, trace and ultratrace concentrations of Ag, Al, As, Au, Ba, Be, Br, Ca, Cd, Ce, Cl, Co, Cr, Cs, Cu, Dy, Eu, Fe, Ga, Hf, K, La, Li, Lu, Mg, Mn, Na, Nb, Ni, P, Pb, Sb, Sc, Se, Sm, Sn, Sr, Ta, Th, Ti, U, V, W and Zn in crude juice, principal juice, sirup juice (produced during the successive stages of sugar industry), sugar cane plant, molasses, deposits (produced as a result of the addition of Ca(OH)2 and superphosphate and passage of SO2 through juice), A-and B-sugar and soil samples have been determined by destructive and nondestructive instrumental neutron activation (INAA), atomic absorption spectrophotometric (AAS) and inductively coupled plasma-atomic emission spectrometric (ICP-AES) analyses. The results obtained by the methods applied are in excellent agreement. Concentrations of the elements are different. Variations in element concentrations in cance plants and in crude juice may be attributed to composition changes or different botanical structures; in mixed juice, sirup, molasse and deposits they may be due to chemical treatments or corrosion effects on containers, whereas in soil samples to geochemical and biogeochemical fractionation as a result of adsorption and uptake of trace elements by plants from surrounding soil solutions.

Keywords

Fractionation Cane Sugar Cane Soil Solution Neutron Activation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    H. A. V. D. SLOOT, J. B. LUTEN, Report, Petten, Netherlands, 1976.Google Scholar
  2. 2.
    H. A. V. D. SLOOT, Report ECN-1, Petten Netherlands, 1976.Google Scholar
  3. 3.
    J. WIJKSTRA, H. A. V. D. SLOOT, Report ECN-78-110, Petten, Netherlands, 1978.Google Scholar
  4. 4.
    G. D. WALS, H. A. V. D. SLOOT, R. MASSEE, Report ECN-80-008, Petten, Netherlands, 1980Google Scholar
  5. 5.
    M. K. SHERIF, R. M. AWADALLAH, F. GRASS, Bull. Fac. Sci., Assiut Univ., Egypt, 7 (1978) 379.Google Scholar
  6. 6.
    M. K. SHERIF, R. M. AWADALLAH, F. GRASS, J. Radioanal Chem., 60 (1980) 267.Google Scholar
  7. 7.
    M. K. SHERIF, R. M. AWADALLAH, F. GRASS, J. Chem. Erde, 40 (1981) 178.Google Scholar
  8. 8.
    R. M. AWADALLAH, J. Indian Chem. Soc., (1983) (in press).Google Scholar
  9. 9.
    R. M. AWADALLAH, Asw. Sci. Tech. Bull., 5 (1984) 77.Google Scholar
  10. 10.
    K. R. SHAH, R. H. FILBY, A. I. DAVIS, Int. J. Environ. Anal. Chem., 1, (1971) 63.PubMedGoogle Scholar
  11. 11.
    R. E. JERVIS, D. DEBRUN, W. LEPAGE, B. TIEFENBAC, Report, Univ. Toronto, Toronto, 1970.Google Scholar
  12. 12.
    J. T. TANNER, M. H. FRIEDMAN, U. S. Food and Drug Administration, Division of Chemistry and Physics, Washington, DC, 20 204 USA, 1976.Google Scholar
  13. 13.
    D. HOEDE, R. MASSEE, H. A. DAS, Radiochem. Radioanal Lett., 23 (1975) 379.Google Scholar
  14. 14.
    H. A. V. D. SLOOT, G. D. WALS, C. A. WEERS, H. A. DAS, Report ECN-79-096, Petten, Netherlands, 1979.Google Scholar
  15. 15.
    D. HOEDE, H. A. V. D. SLOOT, Report ECN-79-095, Petten, Netherlands, 1979.Google Scholar
  16. 16.
    F. J. FLANAGAN, Geochim. Cosmochim. Acta, 37 (1973) 1189.Google Scholar
  17. 17.
    H. A. V. D. SLOOT, J. ZONDERHUIS, Report ECN-79-094, Petten, Netherlands, 1979.Google Scholar
  18. 18.
    M. K. SHERIF, R. M. AWADALLAH, A. E. MOHAMED, Bull. Fac. Sci. Assiut Univ., Egypt, 7 (1978) 341.Google Scholar
  19. 19.
    M. K. SHERIF, R. M. AWADALLAH, A. E. MOHAMED, J. Radioanal Chem., 53 (1979) 145.Google Scholar
  20. 20.
    M. K. SHERIF, R. M. AWADALLAH, A. H. AMRALLAH, J. Radioanal Chem., 57 (1980) 53.Google Scholar
  21. 21.
    F. GRASS, R. NIESNER, Nucl. Instr. Methods, 151, (1978) 589.Google Scholar
  22. 22.
    R. M. AWADALLAH, M. K. SHERIF, A. E. MOHAMED, F. GRASS, Intern. J. Environ. Anal. Chem., in press.Google Scholar
  23. 23.
    R. M. AWADALLAH, M. K. SHERIF, A. E. MOHAMED, F. GFASS, Intern. J. Environ. Anal. Chem., in press.Google Scholar
  24. 24.
    G. HENKE, J. Radioanal. Chem., 39 (1977) 69.Google Scholar
  25. 25.
    S. S. BERMAN, J. W. MELAREN, S. N. WILLIE, Anal. Chem., 52 (1980) 488.Google Scholar
  26. 26.
    D. W. HAUSDER, L. T. TAYOR, Anal. Chem., 53 (1981) 1223.Google Scholar
  27. 27.
    J. W. MCLAREN, S. S. BERMAN, J. V. BOYKO, D. S. RUSSEL, Anal. Chem., 53 (1981) 1802.Google Scholar
  28. 28.
    R. W. KUENEN, K. A. WOLRIK, F. L. FRICKE, J. A. CARSISO Anal. Chem., 54 (1982) 2146.Google Scholar
  29. 29.
    J. T. H. ROOS, W. J. PRICE, J. Sci. Fd. Agric., 21 (1970) 51.Google Scholar
  30. 30.
    R. R. BECKER, A. VEGLIA, E. R. SCHMID, J. Radiochem. Radioanal. Lett., 19 (1974) 343.Google Scholar
  31. 31.
    E. A. TASKAEV, D. APOSTOLOV, J. Radioanal. Chem. (1982) 285.Google Scholar
  32. 32.
    R. M. AWADALLAH, M. Sc. Thesis, Assiut Univ., Egypt (1971).Google Scholar
  33. 33.
    O. BRANSTATTER, F. GIRSIG, F. GRASS, R. FLENK, Nucl. Instr. Methods, 104 (1972) 45.Google Scholar
  34. 34.
    C. P. MALIK, A. K. SRIVASTAVA, Textbook of Plant Physiology, New Delhi, Ludhiana, 1982.Google Scholar
  35. 35.
    D. J. F. BOWLING, Uptake of Ions by Plant Roots, Chapman & Hall, London, 1976.Google Scholar
  36. 36.
    M. GIBBS, Structure and Function of Chloroplasts, Springer-Verlag, New York, 1978.Google Scholar
  37. 37.
    R. J. WEAVER, Plant Growth Substances in Agriculture, W. H. Freeman & Co., San Francisco, 1972.Google Scholar
  38. 38.
    R. D. JOHNSON, D. D. MANSKE, Pestic. Monit. J. 9 (1976) 157.PubMedGoogle Scholar
  39. 39.
    D. D. MANSKE, P. E. CORNELIUSSEN, Pestic. Monit. J. 8 (1974) 110.PubMedGoogle Scholar
  40. 40.
    E. J. UNDERWOOD, Toxicants Occurring Naturally in Foods, National Academy of Sciences, 1973, p. 43.Google Scholar
  41. 41.
    E. W. RUSSELL, Soil Conditions and Plant Growth The English Language Book Society & Longman, London, 1973.Google Scholar

Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • R. M. Awadallah
    • 1
  • M. K. Sherif
    • 1
  • A. E. Mohamed
    • 1
  • F. Grass
    • 2
  1. 1.Chemistry DepartmentFaculty of ScienceAswan(Egypt)
  2. 2.Atominstitut der Österreichischen UniversitätenWien(Austria)

Personalised recommendations