Dioxygen evolution from aqueous acid solutions of ruthenium complexes with nitrogen-containing ligands
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Abstract
Some peculiarities of reduction of one-electron oxidants, Ru(bpy) 3 3+ and Ru(bpy)2(py) 2 3+ , in the absence of catalysts (when oxidation of the oxidant's ligands occurs) and in their presence (when also oxidation of water to dioxygen occurs) are discussed. Both oxidation reactions are thought to have a common intermediate.
Keywords
Oxidation Physical Chemistry Catalysis Acid Solution Ruthenium
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Abstract
Описаны некоторые особенности восстановления одноэлектронных окислителей Ru(bpy) 3 3+ и Ru(bpy)2(py) 2 3+ в отсутствии катализаторов (реация окисления ли-ганда) и в их присутствии (реакция окисления воды до дикислорода). Высказано предположение, что обе реакции проходят через общий интермедиат.
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References
- 1.K. I. Zamaraev, V. N. Parmon: Usp. Khim.,49, 1453 (1980).Google Scholar
- 2.G. L. Elizarova, L. G. Matvienko, N. V. Lozhkina, V. N. Parmon, K. I. Zamaraev: React. Kinet. Catal. Lett.,16, 191 (1981).Google Scholar
- 3.G. L. Elizarova, L. G. Matvienko, N. V. Lozhkina, V. E. Maizlish, N. V. Parmon: Ibid.,16, 285 (1981).Google Scholar
- 4.A. Schilt: Analytical Applications of 1,10-phenantroline and Related Compounds. Oxford 1969.Google Scholar
- 5.J. N. Braddock, T. J. Meyer: J. Amer. Chem. Soc.,95, 3158 (1973).Google Scholar
- 6.V. Ya. Shafirovich, N. K. Khannanov, A. E. Shilov: J. Inorg. Biochem.,15, 113 (1981).Google Scholar
- 7.B. A. Moyer, T. J. Meyer: Inorg. Chem.,20, 436 (1981).Google Scholar
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© Akadémiai Kiadó 1983