Reaction Kinetics and Catalysis Letters

, Volume 27, Issue 1, pp 47–51 | Cite as

Micelle-Catalyzed oxidative demethylation of N,N-dimethylaniline in its reactions with oxygen and hydroperoxides

  • A. N. Eremin
  • D. I. Metelitsa
Article
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Abstract

Reversed micelles of the sodium salt of di-(2-ethyl-hexyl)sulfosuccinic acid (Aerosol OT) in octane catalyze the oxidative demethylation of N,N-dimethylaniline in its reactions with molecular oxygen and/or cumene hydroperoxide. Without surfactant no demethylation takes place at 40°C.

Keywords

Oxygen Sodium Physical Chemistry Surfactant Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Обращенные мицеллы натриевой соли ди-(2-этил)-гексилового эфира суляфоянтарной кислоты (аэрозоля OT) в октане ускоряют окислителяное деметилирование N,N-диметиланилина в реакциях с кислородом и/или гидроперекисью кумила. В отсутствие мицеллообразователя деметилирования N,N-диметиланилина в октане при 40°C не происходит.

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Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • A. N. Eremin
    • 1
  • D. I. Metelitsa
    • 1
  1. 1.Institute of Bioorganic ChemistryMinskUSSR

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