Spectroscopic studies of iron(III) complexes of D-saccharose and D-glucose in the solid state and in solution
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Abstract
Iron(III) complexes of D-saccharose and D-glucose were prepared. The compositions of the complexes were determined by standard analytical methods. The Mössbauer spectra reflected the presence of high-spin iron(III) in the polynuclear species. EPR spectroscopy demonstrated antiferromagnetically coupled iron(III) centers within the solid complexes. The13C NMR spectra indicated the presence of a mixture of coordination isomers of iron(III) complexes containing the sugar ligand in differently bound forms.
Keywords
Iron Spectroscopy Sugar Physical Chemistry Inorganic Chemistry
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References
- 1.P. J. CHARLEY, B. SARKAR, C. F. STITT, P. SALTMAN, Biochim. Biophys. Acta, 69 (1963) 313.PubMedGoogle Scholar
- 2.R. AASA, B. MALMSTRÖM, P. SALTMAN, T. VÄNNGÄRD, Biochim. Biophys. Acta, 80 (1964) 430.Google Scholar
- 3.CH. P. RAO, K. GEETHA, M. S. S. RAGHAVAN, Biometals, 7 (1994) 25.Google Scholar
- 4.M. TONKOVIC, S. MUSIC O. HADZIJA, I. NAGY-CZAKÓ, A. VÉRTES, Acta Chim. Hung., 110 (1982) 197.Google Scholar
- 5.K. BURGER, I. ZAY, G. TAKÁCSI NAGY, Inorg. Chim. Acta, 80 (1983) 231.Google Scholar
- 6.M. TONKOVIC, O. HADZIJA, I. NAGY-CZAKÓ, Inorg. Chim. Acta, 80 (1983) 251.Google Scholar
- 7.V. U. KRAPOV, V. N. KULAKOV, V. H. SHAFRANSKY, R. A. SZTUKAN, V. I. SZTANKO, Izotopenpraxis, 6 (1974) 227.Google Scholar
- 8.L. NAGY, K. BURGER, J. KÜRTI, M. A. MOSTAFA, L. KORECZ, I. KIRICSI, Inorg. Chim. Acta, 124 (1986) 55.Google Scholar
- 9.S. WOLOWIEC, K. DRABENT, J. Radioanal. Nucl. Chem., 95 (1985) 1.Google Scholar
- 10.J. KÜRTI, M. A. MOSTAFA, L. KORECZ, L. NAGY, K. BURGER, J. Radioanal. Nucl. Chem., 118 (1987) 437.Google Scholar
- 11.L. NAGY, H. OHTAKI, T. YAMAGUCHI, M. NOMURA, Inorg. Chim. Acta, 159 (1989) 201.Google Scholar
- 12.I. ZAY, A. VÉRTES, G. TAKÁCSINAGY, M. SUBA, K. BURGER, J. Radioanal. Nucl. Chem., 88 (1985) 343.Google Scholar
- 13.K. BURGER, L. NAGY, Metal complexes of carbohydrates and sugar-type ligands, in: Biocoordination Chemistry; Coordination Equilibria in Biologically Active Systems, K. BURGER (Ed.), Ellis Horwood, 1990, Ch. VI, p. 236.Google Scholar
- 14.A. TZSCHACH, K. PÖNICKE, L. KORECZ, K. BURGER, J. Organomet. Chem., 59 (1973) 199.Google Scholar
- 15.H. W. RICH, K. HEGETSCHWEILER, H. M. STREIT, I. ERNI, W. SCHNEIDER, Inorg. Chim. Acta, 187 (1991) 9.Google Scholar
- 16.H. YOKOI, Y. MORI, T. MITANI, S. KAWATA, Bull. Chem. Soc. Japan, 65 (1992) 1898.Google Scholar
- 17.K. S. MURRAY, Coord. Chem. Rev., 12 (1974) 1.Google Scholar
- 18.J. A. THICH, C. CHIH-OU, D. POWERS, B. VASSILION, D. MASTROPAOLO, J. A. POTENZA, H. J. SCHUGAR, J. Am. Chem. Soc., 98 (1976) 1425.Google Scholar
- 19.L. BORERE, L. THALKEN, C. CECCARELLI, M. GLICK, J. H. ZHANG, W. M. REIFF, Inorg. Chem., 22 (1983) 1719.Google Scholar
- 20.G. M. ESCANDAR, A. C. OLIVIERI, M. GONZALEZ-SIERRA, L. F. SALA, J. Chem. Soc. Dalton Trans., (1994) 1189.Google Scholar
- 21.B. LADESIC, D. KANTOCI, H. MEIDER, O. HADZIJA, J. Inorg. Biochem., 48 (1992) 55.PubMedGoogle Scholar
- 22.Y. MORI, H. YOKOI, Bull. Chem. Soc. Japan, 67 (1994) 2724.Google Scholar
- 22.I. SOLOMON, Phys. Rev., 99 (1955) 559.Google Scholar
- 23.N. BLOEMBERGEN, L. O. MORGAN, J. Chem. Phys., 34 (1961) 842.Google Scholar
- 24.B. COXON, Develop. Food Carbohydr., 2 (1980) 351.Google Scholar
- 25.I. ZAY, F. GAIZER, K. BURGER, Inorg. Chim. Acta, 80 (1983) L9.Google Scholar
- 26.M. TONKOVIC, Carbohydr. Res., 254 (1994) 277.PubMedGoogle Scholar
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