Reaction Kinetics and Catalysis Letters

, Volume 51, Issue 1, pp 125–134 | Cite as

Alkylation of aromatics on p-containing ZSM-5 zeolites

  • V. N. Romannikov
  • A. J. Tissler
  • R. Thome
Article
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Abstract

The catalytic activity of ZSM-5 zeolites, modified with phosphorus compounds, has been studied in benzene and toluene alkylation by ethylene. Concentration of acid sites of different nature in the samples was characterized by IR spectroscopy of OH-groups and adsorbed CO. Modification was shown to decrease the concentrations of both strong protic and non-aprotic sites. New acid sites are assumed to appear in P-containing zeolites. The strength of acid sites in the zeolites is supposed to follow the sequence:[[SiOAl]H]≫[POH]> >[MgOH. Activity and regioselectivity of P-containing zeolites are considered to depend on the nature and concentration of the acid sites.

Keywords

Spectroscopy Ethylene Physical Chemistry Phosphorus Benzene 
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References

  1. 1.
    N. Y. Chen, W. E. Garwood: Catal. Rev.-Sci. Eng.,28, 185 (1986).Google Scholar
  2. 2.
    W. Kaeding, C. Chu, L. B. Young, B. Weinstein, S. A. Butter: J. Catal.,67, 159 (1981).Google Scholar
  3. 3.
    F. Lónyi, J. Engelhart, I. Bankós: Proc. 6th Int. Petrochem. Symp., Kozubnic, Poland,2, 403 (1988).Google Scholar
  4. 4.
    J. C. Vedrine, A. Auroux, P. Dejaifve, V. Ducarme, H. Hoser, S. Zhou: J. Catal.,73, 147 (1982).Google Scholar
  5. 5.
    J. A. Lercher, G. Rumplmayer, H. Noller: Proc. Int. Symp. Zeolite Catal., Szeged, 1985; Acta Phys. Chem. Szeged, 71 (1985).Google Scholar
  6. 6.
    W. Reschetilowski, W.-D. Einicke, B. Meier, E. Brunner, H. Ernst: “Zeolites: Facts, Figures, Future”, Stud. Surf. Sci. Catal., Vol. 49, p. 119. Elsevier, Amsterdam 1989.Google Scholar
  7. 7.
    S. M. Csicsery: Pure and Appl. Chem.,58, 841 (1986).Google Scholar
  8. 8.
    J. Dwyer: Chem. Ind. (London), 258 (1984).Google Scholar
  9. 9.
    J.-H. Kim, S. Namba, T. Yashima: “Zeolites as Catalysts, Sorbents and Detergent Builders” Stud. Surf. Sci. Catal., Vol. 46, p. 71. Elsevier, Amsterdam 1989.Google Scholar
  10. 10.
    V. N. Romannikov, E. A. Paukshtis, K. G. Ione: “Chemistry of Microporous Crystals”, Stud. Surf. Sci. Catal., Vol. 60, p. 311. Kodansha-Elsevier, Tokyo-Amsterdam 1991.Google Scholar
  11. 11.
    V. N. Romannikov, S. V. Filimonova, V. M. Mastikhin: React. Kinet. Catal. Lett.,51, 109 (1993).Google Scholar
  12. 12.
    V. N. Romannikov, K. G. Ione: J. Mol. Catal.,31, 251 (1985).Google Scholar
  13. 13.
    K. Ingold: Theoretical Foundations of Organic Chemistry (in Russian) Mir, Moscow 1973.Google Scholar
  14. 14.
    N. V. Choudary, R. V. Jasra, S. G. T. Bhat, T. S. R. Prasada Rao: “Zeolites: Facts, Figures, Future”, Stud. Surf. Sci. Catal., Vol. 49 (B), p. 867. Elsevier, Amsterdam 1989.Google Scholar
  15. 15.
    B. S. Rao, V. R. Chumbhale, I. Balakrishnan, R. A. Shaikh: Proc. 3rd Indian-Soviet seminar on catalysis, vol. 1, p. 113. Institute of Catalysis, Novosibirsk 1988.Google Scholar

Copyright information

© Akadémiai Kiadó 1993

Authors and Affiliations

  • V. N. Romannikov
    • 1
  • A. J. Tissler
    • 2
  • R. Thome
    • 2
  1. 1.Boreskov Institute of CatalysisNovosibirskRussia
  2. 2.VAW AGBonn 1Germany

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