Reaction Kinetics and Catalysis Letters

, Volume 4, Issue 2, pp 221–227 | Cite as

Isomerization and dehydrobromination of 1-bromo-2-methylpropane on alumina modified with alkali halides

  • A. Lycourghiotis
  • N. A. Katsanos
Article

Abstract

The kinetics of the dehydrobromination of 1-bromo-2-methylpropane on alumina modified with NaI and KI have been investigated. A mechanism for the isomerization reactions on alumina modified with alkali halides is proposed in order to explain the catalytic behavior of iodide ion as compared with that of chloride and bromide ions, reported in a previous paper.

Keywords

Alumina Chloride Physical Chemistry Bromide Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Выла исследована кинетика дегидробромирования 1-бром-2-метилпропана на окиси алюминия, модифицированной NaJ и KJ. Для объяснения каталитического поведения иодидных ионов, сравниваемого с поведением хлоридных и бромидных ионов, описанным в предыдущем сообщении, предлагается механизм реакций изомеризации, протекающих на окиси алюминия модифицированной щелочными галидами.

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References

  1. 1.
    I. Hadzistelios, H. J. Sideri-Katsanou, N. A. Katsanos: J. Catal.,27, 16 (1972).Google Scholar
  2. 2.
    A. Lycourghiotis, N. A. Katsanos, I. Hadzistelios: J. Catal.,36, 385 (1975).Google Scholar
  3. 3.
    A. Lycourghiotis: Thesis, University of Patras, Greece.Google Scholar
  4. 4.
    C. S. G. Phillips, A. J. Hart-Davies, R. G. L. Saul, J. Wormald: J. Gas Chromatogr.,5, 424 (1967).Google Scholar

Copyright information

© Akadémiai Kiadó 1976

Authors and Affiliations

  • A. Lycourghiotis
    • 1
  • N. A. Katsanos
    • 1
  1. 1.Physical Chemistry LaboratoryUniversity of PatrasGreece

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