Reaction Kinetics and Catalysis Letters

, Volume 4, Issue 2, pp 191–198 | Cite as

The simplest catalytic mechanism permitting several steady states of the surface

  • V. I. Bykov
  • V. I. Elokhin
  • G. S. Yablonskii
Article

Abstract

The conditions for the existence of several steady states of the surface have been found for the simplest mechanism without the assumption of autocatalysis and without the effect of the medium on the catalyst. A possibility has been shown for the explanation of the multiplicity of steady states, found experimentally in the kinetic region, in terms of mechanisms including interactions between various intermediates.

Abstract

Получены условия существования нескольких стационарных состояний поверхности для простейшего механизма без предположения об автокатализе и воздействия реакционной среды на катализатор. Показана возможность объяснения множественности стационарных состояний, найденных экспериментально в кинетической области, в рамках механизмов, включающих стадии взаимодействий между различными промежуточными вешествами.

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Copyright information

© Akadémiai Kiadó 1976

Authors and Affiliations

  • V. I. Bykov
    • 1
  • V. I. Elokhin
    • 1
  • G. S. Yablonskii
    • 1
  1. 1.Institute of CatalysisNovosibirskUSSR

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