Hyperfine Interactions

, Volume 28, Issue 1–4, pp 781–784 | Cite as

Chemical transport reactions in the In-Sn-S ternary system: Existence of tin (II) and tin (IV) atoms by Mössbauer effect of119Sn in the isolated compounds

  • Josette Olivier-Fourcade
  • Claire Adenis
  • Jean -Claude Jumas
  • Etienne Philippot
Electronic Structure, Chemistry
  • 19 Downloads

Abstract

Iodine vapour transport, carried out in the In-Sn-S ternary system leads to single crystals with quite different morphologies: needles, sticks, sheets and polyhedra. The two oxidation states of tin atoms are shown for all these phases by119Sn Mössbauer effect. A varying relative proportion of tin(IV) — tin(II) is observed according to the different crystal forms.

Keywords

Oxidation Thin Film Iodine Oxidation State Ternary System 
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References

  1. /1/.
    Applications of Solid Electrolytes, Ed.T. Takahashia and A. Kozawa, J.Ec. Press.Google Scholar
  2. /2/.
    O. Mootz and H. Puhl, Acta Crystallogr. 23(1967)471.Google Scholar
  3. /3/.
    J.C. Jumas, J. Olivier-Fourcade, E. Philippot and M. Maurin, Rev. Chim. Minér. 18(1981)33.Google Scholar
  4. /4/.
    C. Adenis and J. Olivier-Fourcade, Calorimétrie et Analyse Thermique Vol. XVI (1985)48.Google Scholar
  5. /5/.
    J. Padiou, J.C. Jumas and M. Ribes, Rev. Chim. Minér. 18(1981)33.Google Scholar
  6. /6/.
    M. Katada, Journal of Science of the Hiroshima University 39(1975)45.Google Scholar
  7. /7/.
    E. Riedel and W. Morlok, Z. Anorg. Allg. Chem. 438(1978)233.Google Scholar
  8. /8/.
    P. Colombet, M. Danot and J. Rouxel, Rev. Chem. Minér. 16(1979)179.Google Scholar
  9. /9/.
    J.C. Jumas, S. Del Bucchia, E. Philippot and M. Maurin, J. Solid. State Chem. 41(1982)50.Google Scholar

Copyright information

© J.C. Baltzer A.G., Scientific Publishing Company 1986

Authors and Affiliations

  • Josette Olivier-Fourcade
    • 1
  • Claire Adenis
    • 1
  • Jean -Claude Jumas
    • 1
  • Etienne Philippot
    • 1
  1. 1.Laboratoire de Physicochimie des Matériaux SolidesUA 407 CNRS, Université des Sciences et Techniques du Languedoc, Place Eugène BataillonMontpellier CedexFrance

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