Gamma radiolysis of solutions of carbon tetrachloride in secondary alcohols

  • G. Radhakrishna
  • Ch. Sudhakar
  • V. R. S. Rao
Article
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Abstract

Oxidation of cyclohexanol free from peroxide by carbon tetrachloride under the influence of gamma radiation was carried out both for air saturated and deareated systems. Large values for the formation of HCl are obtained. A kinetic expression consistent with experimental observations has been derived.

Keywords

Oxidation Radiation Alcohol Physical Chemistry Peroxide 
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References

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    K. HANNERZ, Research, 9 (1956) 81.Google Scholar
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    W. V. SHERMAN, C. RADLOWSKI, J. Phys. Chem., 74 (1970) 3043.Google Scholar
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    V. KRAVTOCHVIL, J. BUTUSEK, Chem. Prum., 16 (1966) 715.Google Scholar

Copyright information

© Akadémiai Kiadó 1984

Authors and Affiliations

  • G. Radhakrishna
    • 1
  • Ch. Sudhakar
    • 1
  • V. R. S. Rao
    • 1
  1. 1.Department of ChemistryIndian Institute of TechnologyMadras(India)

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