Journal of thermal analysis

, Volume 46, Issue 3–4, pp 965–972

The glass transition temperature of polystyrene

Results of a round robin test
  • J. Rieger


A round robin test was performed to determine the reliability of values for the glass transition temperatureTg as determined by DTA on polymers. Ten different instruments were involved. The test material was high molecular weight polystyrene. Values forTg (midpoint) were reported in the range 107°C±2 K. The respective heat flow curves differed considerably in shape. In the literature aTg of 100°C is often given for polystyrene. The discrepancy between this value and the value of 107°C found in the round robin test is due to three differences: the thermal history of the sample, the evaluation of the heat flow curves, and the effect of finite sample size.


glass transition temperature polystyrene 


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  1. 1.
    B. Wunderlich, D. M. Bodily and M. H. Kaplan, J. Appl. Phys., 35 (1964) 95.CrossRefGoogle Scholar
  2. 2.
    E.-J. Donth, Relaxation and Thermodynamics in Polymers, Akademie Verlag, Berlin 1992.Google Scholar
  3. 3.
    G. B. McKenna, in: Comprehensive Polymer Science, Vol. 2, Pergamon, Oxford 1989.Google Scholar
  4. 4.
    B. Wunderlich, Thermal Analysis, Academic Press, NY 1990.Google Scholar
  5. 5.
    M. J. Richardson, in: Calorimetry and Thermal Analysis of Polymers, Hanser Publ., Munich Chap. 6, 1994.Google Scholar
  6. 6.
    L. Aras and M. J. Richardson, Polymer, 30 (1989) 2246.CrossRefGoogle Scholar
  7. 7.
    ASTME 1356-91.Google Scholar
  8. 8.
    M. J. Richardson, in: Comprehensive Polymer Science, Vol. 2, Pergamon, Oxford 1989.Google Scholar
  9. 9.
    M. J. Richardson and N. G. Savill, Polymer, 16 (1975) 753.CrossRefGoogle Scholar
  10. 10.
    H. Toratani, K. Shiokawa and K. Takamizawa, Rep. Progr. Polym. Phys. Japan, 37 (1994) 339.Google Scholar

Copyright information

© Akadémiai Kiadó 1996

Authors and Affiliations

  • J. Rieger
    • 1
  1. 1.Polymer Research DivisionBASF AGLudwigshafenGermany

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