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Journal of thermal analysis

, Volume 50, Issue 3, pp 463–471 | Cite as

Spectrophotometric analysis, thermal analysis and gravimetric determination of some metal ions with oxime and Schiff's base derivatives of N-furoylphenylhydroxylamine

  • M. M. Moustafa
Article

Abstract

The oxime and Schiff's base of N-furoylphenylhydroxylamine form complexes with Co2+, Cu2+, Zn2+ and Fe3+. These complexes were studied by means of the UV — Vis. spectra of nujol mulls, electron spin resonance (ESR) spectra and magnetic susceptibility to determine their stereochemistry. The complexes were characterized via elemental analyses, molar conductivities and thermogravimetric analyses. Organic reagents were used for the gravimetric determination of Co2+, Cu2+ and Fe3+ through the precipitation of their complexes. The compounds were also used for separation of a binary mixture of Cu2+ and Cu2+. Interferences were studied.

Keywords

analyses of metal chelates determination of stereochemistry 

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Copyright information

© Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest 1997

Authors and Affiliations

  • M. M. Moustafa
    • 1
  1. 1.Chemistry Department, Faculty of ScienceBenha UniversityBenha, KalubiaEgypt

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