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Synthesis of organo-platinum(II) and -palladium(II) complexes ofN-phenyl- andN-(p-Tolyl)pyrazole

Summary

When platinum(II) chloride dissolved in acetic acid containing concentrated hydrochloric acid was refluxed withN-phenylpyrazole(liphpz) andN-(p-tolyl)pyrazole (Htlpz), complexes of composition [Pt(N-C)Cl]2 (N-C = phpz, tlpz) were obtained, in which phpz and tlpz are coordinated through nitrogen and carbon forming a five membered metallocycle. Similar palladium(II) complexes [Pd(N-C)Cl]2 were easily prepared by the reaction of palladium(II) chloride with Hphpz and Htlpz in methanol in the presence of lithium chloride. These [M(N-C)CI]2 complexes reacted with tri-n-butylphosphine (PBu3) and pyridine (py) to give the adducts [M(N-C)ClL](L = PBu3, py). Ethylenediamine(en) and acetylacetone(Hacac) gave IPd(phpz)(en)]Cl and [Pd(phpz)(acac)] respectively. These new complexes are characterized by means of1H-n.m.r. and i.r. spectra, and probable structures are proposed.

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Correspondence to Matsuo Nonoyama.

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Nonoyama, M., Takayanagi, H. Synthesis of organo-platinum(II) and -palladium(II) complexes ofN-phenyl- andN-(p-Tolyl)pyrazole. Transition Met Chem 1, 10–13 (1975). https://doi.org/10.1007/BF01753073

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Keywords

  • Chloride
  • Lithium
  • Acetic Acid
  • Platinum
  • Catalysis