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Spin-orbit coupling in nitrite ion and nitrite salts

Abstract

The absorption intensity of the3B11A1 transition of nitrite salts of the non-transition metals is markedly dependent on the metal counterion and is causative of the yellow-orange colors of the heavier-metal salts. It is assumed that spin-orbit coupling is responsible for this phenomenon; this assumption is investigated here using semi-empirical one-electron calculations and is validated. The subjects of covalent bonding in metal salts, charge transfer transitions in such systems and the S j ← S 0 electronic spectroscopy of nitrite salts are also investigated.

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References

  1. [1]

    Maria H. J., Armstrong A. T., McGlynn S. P.: J. Chem. Phys.45 (1968), 2735.

  2. [2]

    Maria H. J., Wahlborg A., McGlynn S. P.: J. Chem. Phys.49 (1968), 4925;

  3. [2a]

    Maria H. J., Srinivasan B. N., McGlynn S. P.: Molecular Luminescence, Ed. by E. C. Lim. W. A. Benjamin, Inc., New York 1969.

  4. [3]

    Maria H. J., Armstrong A. T., McGlynn S. P.: J. Chem. Phys.50 (1969), 2777.

  5. [4]

    Hochstrasser R. M., Marchetti A. P.: J. Chem. Phys.50 (1969), 1727.

  6. [5]

    Allen W. C., Dixon R. N.: Trans. Faraday Soc.65 (1969), 1168.

  7. [6]

    Carroll D. G., Armstrong A. T., McGlynn S. P.: J. Chem. Phys.44 (1966), 1865.

  8. [7]

    Fenske R. F., Caulton K. J., Radtke D. D., Sweeney C. C.: Inorg. Chem.5 (1966), 951.

  9. [8]

    Harris L.: Ph. D. Dissertation, Louisiana State University, New Orleans (Louisiana) 1969.

  10. [9]

    Richardson J. W., Rundle R. E.: ISC-830, U.S. Atomic Energy Commission, Technical Information Service Extension, Oak Ridge (Tennessee) 1956.

  11. [10]

    Cusachs L. C.: J. Chem. Phys.43 (1965), 157S.

  12. [11]

    Cusachs L. C., Reynolds J. W.: J. Chem. Phys.43 (1965), 5160.

  13. [12]

    Moore C. E.: Atomic Energy Levels. U.S. National Bureau of Standards Circular 467, 1949 and 1952.

  14. [13]

    Clementi E.: IBM Research Paper RJ-256, IBM Research Laboratories, San Jose (California) September 6, 1963.

  15. [14]

    Cusachs L. C., Trus B. I., Carroll D. G., McGlynn S. P.: J. Chem. Phys.46 (1967), 1532.

  16. [15]

    Basch H., Gray H. B.: Theor. chim. Acta (Berlin)4 (1966), 367.

  17. [16]

    Carpenter G. B.: Acta Cryst.7 (1954), 73.

  18. [17]

    Long R. E., Marsh R. E.: Acta Cryst.15 (1962), 448.

  19. [18]

    Cusachs L. C., Trus B. L.: J. Chem. Phys.46 (1967), 1532.

  20. [19]

    Carroll D. G., Vanquickenborne L. G., McGlynn S. P.: J. Chem. Phys.45 (1966), 2777.

  21. [20]

    McClure D. S.: J. Chem. Phys.17 (1949), 905.

  22. [21]

    Griffith J. S.: The Theory of Transition Metal Ions. Cambridge University Press, 1961.

  23. [22]

    Trawick W. G., Eberhardt W. H.: J. Chem. Phys.22 (1954), 1462.

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This work was supported by contracts between the United States Atomic Energy Commission — Biology Branch and the United States Air Force with the Louisiana State University.

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Harris, L.E., Maria, H.J. & McGlynn, S.P. Spin-orbit coupling in nitrite ion and nitrite salts. Czech J Phys 20, 1007–1017 (1970). https://doi.org/10.1007/BF01691241

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Keywords

  • Color
  • Spectroscopy
  • Nitrite
  • Charge Transfer
  • Covalent Bonding