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Journal of Molecular Evolution

, Volume 2, Issue 2–3, pp 231–234 | Cite as

Further studies of urea-catalyzed phosphorylation reactions

  • R. Österberg
  • L. E. Orgel
  • R. Lohrmann
Letter to the Editor

Summary

We have analyzed the products formed when mixtures of a nucleoside and ammonium dihydrogen phosphate are heated with an excess of urea. If there is more phosphate than nucleoside in the mixture, compounds containing pyrophosphate bonds are obtained. If uridine, as nucleoside, is in excess over phosphate, di- and oligonucleotides are formed.

Key words

Phosphorylation Nucleotides Nucleoside Polyphosphates Oligonucleotides Urea Prebiotic 

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References

  1. Lohrmann, R., Orgel, L. E.: Science171, 490 (1971).Google Scholar
  2. Moravek, J., Skoda, J.: Coll. Czech. Chem. Commun.32, 206 (1967).Google Scholar
  3. Österberg, R., Orgel, L. E.: J. molec. Evolution1, 241 (1972).Google Scholar
  4. Pfitzner, K. E., Moffatt, J. G.: J. Org. Chem.29, 1508 (1964).Google Scholar
  5. Ponnamperuma, C., Mack, R.: Science148, 1221 (1965).Google Scholar
  6. Sulston, J., Lohrmann, R., Orgel, L. E., Miles, H. T.: Proc. nat. Acad. Sci. (Wash.)59, 726 (1968).Google Scholar

Copyright information

© Springer-Verlag 1973

Authors and Affiliations

  • R. Österberg
    • 1
  • L. E. Orgel
    • 1
  • R. Lohrmann
    • 1
  1. 1.The Salk Institute for Biological StudiesSan DiegoUSA

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