Abstract
The measurements of the spectra of Auger electrons of the silicon surfaces performed at the pressure of (2–5)×10−7 Torr are described. In this pressure range rapid oxidation and carbonization of the uppermost layers take place. The changes of characteristic energies in Auger and loss spectra are related to the change of chemical composition of the surface. The combination of the characteristic loss spectroscopy with Auger electron spectroscopy makes possible the determination of the chemical shifts. The measurements of the chemical shifts of the individual energy levels of the silicon atoms in both the pure and contaminated silicon surfaces, in quartz and Fe∶Si alloy are given. Finally, the possibilities and limitations of the heating for the silicon surface cleaning are examined.
Keywords
Oxidation Silicon Quartz Chemical Shift Energy LevelPreview
Unable to display preview. Download preview PDF.
References
- [1]Chang C. C., Surface Science25 (1971), 53.Google Scholar
- [2]Taylor N. J.,in Techniques of Metal Research, Vol. VII, (Ed. R. F. Bunshah) Interscience, New York 1971.Google Scholar
- [3]Chung M. F., Jenkins L. H., Surface Science22 (1970), 479.Google Scholar
- [4]Bauer E., Z. Phys.224 (1969), 19.Google Scholar
- [5]Siegbahn K. et al., ESCA, Atomic, Molecular and Solid State Structure Studied by Means of Electron Spectroscopy, Almquist and Wiksell Boktryckeri AB, Uppsala 1967.Google Scholar
- [6]Ershov O. A., Lukirskij A. P., Fiz. Tverd. Tela8 (1966), 2137.Google Scholar
- [7]Wei P. S. P., Surface Science20 (1970), 157.Google Scholar
- [8]Chung M. F., Jenkins L. H., Surface Science26 (1971), 649.Google Scholar
- [9]Joyce B. A., Neave J. H., Surface Science27 (1971), 499.Google Scholar
- [10]Carrière B., Deville J. P., Goldsztaub S., C. R. Acad. Sci. Paris274B (1972), 415.Google Scholar
- [11]Chang C. C., Surface Science23 (1970), 283.Google Scholar
- [12]Nicolet M. A., Bilger H. R., Meyer O., Phys. Stat. Sol. (a)3 (1970), 1019.Google Scholar
- [13]Henderson R. C., Marcus R. B., Polito W. J., J. Appl. Phys.42 (1971), 1208.Google Scholar
- [14]Krause G. O., Phys. Stat. Sol. (a)3 (1970), 899.Google Scholar
- [15]Grant J. T., Haas T. W., Surface Science23 (1970), 347.Google Scholar
- [16]Narusawa T., Komiya S., Hiraki A., Appl. Phys. Lett.20 (1972), 272.Google Scholar
- [17]Ridgway J. W. T., Haneman D., Surface Science24 (1971), 451.Google Scholar
- [18]Ridgway J. W. T., Haneman D., Surface Science26 (1971), 683.Google Scholar
- [19]Goldsztaub S., (private communication).Google Scholar
- [20]Baer Y. et. al., Physica Scripta1 (1970), 55.Google Scholar
- [21]Langer D. W., Z. Naturforsch.24a (1969), 1555.Google Scholar
- [22]Mazur R. G., Hickey D. H., J. Electrochem. Soc.113 (1966), 255.Google Scholar
- [23]Wiech G., Z. Physik207 (1967), 428.Google Scholar