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Russian Chemical Bulletin

, Volume 43, Issue 6, pp 1044–1047 | Cite as

Reactions of mercury salts with benzo- and tetrafluorobenzobarrelenes

  • T. N. Sokolova
  • Yu. K. Grishin
  • I. V. Timofeev
  • V. R. Kartashov
Organometallic Chemistry
  • 19 Downloads

Abstract

Regiochemistry and stereochemistry of the addition of mercury salts to benzobarrelene and tetrafluorobenzobarrelene have been studied in acetic acid and methanol. The effect of the substrate structure on the regiochemistry of the reaction is discussed.

Key words

benzobarrelenes, solvo- and azidomercuration regiochemistry regioisomers, structure Hg-double bond coordination, effect on the ratio of isomeric products 

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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • T. N. Sokolova
    • 1
  • Yu. K. Grishin
    • 2
  • I. V. Timofeev
    • 1
  • V. R. Kartashov
    • 1
  1. 1.Nizhnii Novgorod Technical State UniversityNizhnii NovgorodRussian Federation
  2. 2.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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