Formation of μ-acyl complexes via the reactions of alkynes (OC)5MC≡CPh with H2Os3(CO)10 AND HOs3(CO)10(μ-C≡CPh) clusters

  • A. A. Koridze
  • O. A. Kizas
  • N. E. Kolobova
  • P. V. Petrovskii
Organic Chemistry
Received:
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Conclusions

  1. 1.
    Reaction of (OC)5MC≡CPh (M=Mn, Re) alkynes with the HOs3(CO)10(μ-C≡CPH) cluster gave μ-acyl osmium complexes
    .
     
  2. 2.

    Dimethylphenylphosphine has been shown to induce reversible formation of C-C bonds via interconversion of CO and μ-acyl ligands on the surface of the osmium cluster.

     

Keywords

Alkyne Osmium Reversible Formation Osmium Complex Osmium Cluster 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • A. A. Koridze
    • 1
  • O. A. Kizas
    • 1
  • N. E. Kolobova
    • 1
  • P. V. Petrovskii
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic ChemistryAcademy of Sciences of the USSRMoscow

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