Colloid and Polymer Science

, Volume 257, Issue 9, pp 913–919 | Cite as

Electric field-induced structure in poly(acrylonitrile)

  • S. I. Stupp
  • S. H. Carr
Original Contributions Polymer Science

Summary

Experimental evidence has been obtained for alteration of the molecular organization in polyacrylonitrile which has been given a thermoelectric treatment that creates a persistent electrical polarization. These studies have involved infrared spectroscopy and X-ray diffractometry, and their results have been interpreted as suggesting the existence of dipolar clusters in polarized material. These clusters cause polyacrylonitrile chains to adopt a structure which is different from any previously reported for this material. It is suggested that stability of the polarized state of polyacrylonitrile results, in part, from this new molecular organization.

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Copyright information

© Dr. Dietrich Steinkopff Verlag 1979

Authors and Affiliations

  • S. I. Stupp
    • 1
    • 2
  • S. H. Carr
    • 1
  1. 1.Department of Materials Science and Engineering and Materials Research CenterNorthwestern UniversityEvastonUSA
  2. 2.Department of Biological MaterialsNorthwestern UniversityIllinoisChicagoUSA

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