Colloid and Polymer Science

, Volume 257, Issue 11, pp 1203–1206 | Cite as

Reactivity of acrylic monomers

I. Copolymerization of N,N-diethylacrylamide with methyl acrylate
  • E. Dumitriu
  • Sp. Oprea
  • S. Maxim
  • A. Nathanson
  • M. Dima
Original Contributions Polymer Science
Received:

Summary

The copolymerization of N,N-diethylacrylamide (Ml) with methyl acrylate (M2) was investigated and reactivity ratiosr1= 0.41 andr2 = 0.52 obtained. Also the distribution of diad fractions was calculated and the results were interpreted in terms of the product of reactivity ratios. The tendency of the two monomers to alternate was explained on the basis of differences in polatities between the double bonds, this explanation being supported both by the values ofe parameter and NMR spectroscopy data. A copolymerization mechanism was suggested.

Keywords

Polymer Spectroscopy Methyl Physical Chemistry Double Bond 
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Copyright information

© Dr. Dietrich Steinkopff Verlag 1979

Authors and Affiliations

  • E. Dumitriu
    • 1
  • Sp. Oprea
    • 1
  • S. Maxim
    • 1
  • A. Nathanson
    • 1
  • M. Dima
    • 1
  1. 1.Department of Organic Chemistry Faculty of Chemical TechnologyJassyRumania

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