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Russian Chemical Bulletin

, Volume 45, Issue 8, pp 2018–2019 | Cite as

Highly efficient synthesis of trimethylarsine

  • V. V. Gavrilenko
  • L. A. Chekulaeva
  • I. V. Pisareva
Brief Communications
  • 36 Downloads

Abstract

A convenient, highly efficient, and environmentally safe procedure for the preparation of trimethylarsine was proposed. A quantitative yield of this compound in the reaction of As2O3 with AIMe3 was attained for the first time by using mechanochemical activation of the process.

Key words

trimethylarsine trimethylaluminum synthesis ecological safety 

References

  1. 1.
    A. H. Cowley and R. A. Jones,Angew. Chem., Int. Ed. Engl., 1989,28, 1208; P. Zanella, G. Rosetto, N. Brianese, F. Ossola, and M. Porchia, Chem. Mater., 1991,3, 225.Google Scholar
  2. 2.
    R. Kh. Freidlina, inSinteticheskie metody v oblasti metalloorganicheskikh soedinenii mysh'yaka [Synthetic Methods in the Field of Organometallic Compounds of Arsenic], Izd. AN SSSR, Moscow-Leningrad, 1945, 27 (in Russian).Google Scholar
  3. 3.
    G. O. Doake and L. D. Freedmann,Organometallic Compounds of Arsenic, Antimony and Bismuth, John Wiley and Sons, New York, 1970.Google Scholar
  4. 4.
    Houben-Weyl,Methoden der OrganischenChemie, Metallorganische Verbindungen Al, Ga, In, 77, Georg Thieme, Stuttgart, 1970,13/4, 1978,13/8.Google Scholar
  5. 5.
    R. R. Reshaw and G. E. Holm,J. Am. Chem. Soc., 1920,42, 1468.Google Scholar
  6. 6.
    E. G. Claeys,J. Organomet. Chem., 1966,5, 446.Google Scholar
  7. 7.
    L. Fournier and J. G. Riess,Synthes. Inorganic Metal.-Org. Chem., 1972,2, 53.Google Scholar
  8. 8.
    L. I. Zakharkin and O. Yu. Okhlobystin,Izv. Akad. Nauk SSSR, 1959, 1942 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1959 (Engl. Transl.)].Google Scholar
  9. 9.
    H. Jenkner, Ger. Pat. 1.064.513, 1956,Chem. Abstr., 1961,55, 11302a.Google Scholar
  10. 10.
    V. V. Gavrilenko, L. A. Chekulaeva, 1. V. Pisareva, and I. A. Savitskaya,Sposob polucheniya trimetilmysh'yaka [Method for the Synthesis of Trimethylarsine], USSR Pat. No. 1747454,Byull. izobret., No. 26, 15.06.1992; V. V. Gavrilenko,Intern. Symp. Adv. Technologies and Production of Organic and Inorganic Chemistry-95, April 25–28, Moscow, 1995, 38.Google Scholar
  11. 11.
    Jpn. Pat. No. 64-566916 Cl. CO7F9/72, published in 1989.Google Scholar
  12. 12.
    H. Clasen,Angew. Chem., 1961,73, 322.Google Scholar
  13. 13.
    L. I. Zakharkin and V. V. Gavrilenko,Zh. Obshch. Khim., 1962,32, 689 [J. Gen. Chem. USSR, 1962,32 (Engl. Transl.)].Google Scholar

Copyright information

© Plenum Publishing Corporation 1996

Authors and Affiliations

  • V. V. Gavrilenko
    • 1
  • L. A. Chekulaeva
    • 1
  • I. V. Pisareva
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of SciencesMoscowRussian Federation

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