Angle-dependent electron energy spectra resulting from autoionizing Ne⋆ (3s3P2) +H(12S) collisions

  • A. Merz
  • M. -W. Ruf
  • H. Hotop
Article

Abstract

Experimental angle-dependent electron energy spectra for the autoionization complex Ne*(3s3P2)+H(12S), leading to Penning and associative ionization, are reported. The data, measured at thermal collision energies (Ērel∼51 meV), clearly show an angular variation of the spectral shape, indicating that electrons with angular momentuml>0 participate in the autoionization process. The corresponding non-isotropic electron emission leads to a correlation between the impact parameter-dependent heavy-particle dynamics and the observed electron energy spectrum at a certain detection angle. The experimental results are qualitatively discussed in connection with previous work on the system He*(23S)+H(12S). Furthermore, we present quantum mechanical model-calculations for the electron energy spectrum on the basis of available potential data.

PACS

34.50.Gb 33.70.−w 34.50.Lf 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Ruf, M.-W., Yencha, A.J., Hotop, H.: Z. Phys. D5, 9 (1987)Google Scholar
  2. 2.
    Müller, M.W., Bussert, W., Ruf, M.-W., Hotop, H., Meyer, W.: Phys. Rev. Lett.59, 2279 (1987)Google Scholar
  3. 3.
    Waibel, H., Ruf, M.-W., Hotop, H.: Z. Phys. D9, 191 (1988)Google Scholar
  4. 4.
    Mitsuke, K., Kusafuka, K., Ohno, K.: J. Phys. Chem.93, 3062 (1989)Google Scholar
  5. 5.
    Merz, A., Müller, M.W., Ruf, M.-W., Hotop, H., Meyer, W., Movre, M.: Chem. Phys. Lett.160, 377 (1989)Google Scholar
  6. 6.
    Merz, A., Müller, M.W., Ruf, M.-W., Hotop, H., Meyer, W., Movre, M.: Chem. Phys.145, 219 (1990)Google Scholar
  7. 7.
    Hotop, H., Ruf, M.-W., Yencha, A.J., Fricke, B.: Ann. Phys. (Leipzig)47, 635 (1990)Google Scholar
  8. 8.
    Khan, A., Siddiqui, H.R., Siska, P.E.: J. Chem. Phys.95, 3371 (1991)Google Scholar
  9. 9.
    Ohno, K., Takami, T., Mitsuke, K.: J. Chem. Phys.94, 2675 (1991)Google Scholar
  10. 10.
    Merz, A., Ruf, M.-W., Hotop, H.: Phys. Rev. Lett.69, 3467 (1992)Google Scholar
  11. 11.
    Bardou, F., Emile, O., Courty, J.-M., Westbrook, C.I., Aspect, A.: Europhys. Lett.20, 681 (1992)Google Scholar
  12. 12.
    Longley, E.J., Dunlavy, D.C., Falcetta, M.F., Bevsek, H.M., Siska, P.E.: J. Phys. Chem.97, 2097 (1993)Google Scholar
  13. 13.
    Merz, A., Ruf, M.-W., Hotop, H., Movre, M., Meyer, W.: In: AIPConference Proceedings 295. The physics of electronic and atomic collisions, XVIII ICPEAC. Aarhus, Denmark, 1993 Andersen, T., Fastrup, B., Folkmann, F., Knudsen, H., Andersen, N. (eds.), p. 852. New York: American Institute of Physics 1993Google Scholar
  14. 14.
    Rutherford, G.H., Soletzky, P.A., Bryan, W.H., Dunning, F.B., Walters, G.K.: Phys. Rev. A46, 230 (1992)Google Scholar
  15. 15.
    Padial, N.T., Cohen, J.S., Martin, R.L., Lane, N.F.: Phys. Rev. A40, 117 (1989)Google Scholar
  16. 16.
    Müller, M.W., Merz, A., Ruf, M.-W., Hotop, H., Meyer, W., Movre, M.: Z. Phys. D21, 89 (1991)Google Scholar
  17. 17.
    Ishida, T.: Chem. Phys. Lett.211, 1 (1993)Google Scholar
  18. 18.
    Sarpal, B.: J. Phys. B26, 4145 (1993)Google Scholar
  19. 19.
    Movre, M., Meyer, W.: J. Chem. Phys. (submitted for publication)Google Scholar
  20. 20.
    Movre, M., Meyer, W., Merz, A., Ruf, M.-W., Hotop, H.: Chem. Phys. Lett. (submitted for publication)Google Scholar
  21. 21.
    Aguilar, A., Brunetti, B., Gonzalez, M., Vecchiocattivi, F.: Chem. Phys.145, 211 (1990)Google Scholar
  22. 22.
    Aguilar-Navarro, A., Brunetti, B., Falcinelli, S., Gonzalez, M., Vecchiocattivi, F.: J. Chem. Phys.96, 433 (1992)Google Scholar
  23. 23.
    Schohl, S., Müller, M.W., Meijer, H.A.J., Ruf, M.-W., Hotop, H., Morgner, H.: Z. Phys. D16, 237 (1990)Google Scholar
  24. 24.
    Khan, A., Siddiqui, H.R., Siska, P.E.: J. Chem. Phys.94, 2588 (1991)Google Scholar
  25. 25.
    Baudon, J., Feron, P., Miniatura, C., Perales, F., Reinhardt, J., Robert, J., Haberland, H., Brunetti, B., Vecchiocattivi, F.: J. Chem. Phys.95, 1801 (1991)Google Scholar
  26. 26.
    Lorenzen, J., Hotop, H., Ruf, M.-W., Morgner, H.: Z. Phys. A297, 19 (1980)Google Scholar
  27. 27.
    Lorenzen, J., Morgner, H., Bußert, W., Ruf, M.-W., Hotop, H.: Z. Phys. A310, 141 (1983)Google Scholar
  28. 28.
    Niehaus, A.: Phys. Rep.186, 149 (1990)Google Scholar
  29. 29.
    Morgner, H.: J. Phys. B12, 2171 (1979)Google Scholar
  30. 30.
    Hickman, A.P., Morgner, H.: J. Phys. B9, 1765 (1976)Google Scholar
  31. 31.
    Ebding, T., Niehaus, A.: Z. Phys.270, 43 (1974)Google Scholar
  32. 32.
    Morgner, H., Niehaus, A.: J. Phys. B12, 1805 (1979)Google Scholar
  33. 33.
    Merz, A., Ruf, M.-W., Hotop, H., Movre, M., Meyer, W.: J. Phys. B (accepted for publication)Google Scholar
  34. 34.
    Schohl, S., Klar, D., Kraft, T., Meijer, H.A.J., Ruf, M.-W., Schmitz, U., Smith, S.J., Hotop, H.: Z. Phys. D21, 25 (1991)Google Scholar
  35. 35.
    Miller, W.H.: J. Chem. Phys.52, 3563 (1970)Google Scholar
  36. 36.
    Niehaus, A.: Adv. Chem. Phys.45, 399 (1981)Google Scholar
  37. 37.
    Micha, D.A., Nakamura, H.: Phys. Rev. A11, 1988 (1975)Google Scholar
  38. 38.
    Rosmus, P., Reinsch, E.-A.: Z. Naturforsch.35a, 1066 (1980)Google Scholar
  39. 39.
    Gianturco, F.A., Niedner, G., Noll, M., Semprini, E., Stefani, F., Toennies, J.P.: Z. Phys. D7, 281 (1987)Google Scholar
  40. 40.
    Zemke, W.T., Olson, R.E., Verma, K.K., Stwalley, W.C., Liu, B.: J. Chem. Phys.80, 356 (1984)Google Scholar
  41. 41.
    Siska, P.E.: (private communication)Google Scholar
  42. 42.
    Bieniek, R.J.: Phys. Rev. A18, 392 (1978)Google Scholar
  43. 43.
    Siska, P.E.: Rev. Mod. Phys.65, 2 (1993)Google Scholar

Copyright information

© Springer-Verlag 1994

Authors and Affiliations

  • A. Merz
    • 1
  • M. -W. Ruf
    • 1
  • H. Hotop
    • 1
  1. 1.Fachbereich PhysikUniversität KaiserslauternKaiserslauternGermany

Personalised recommendations