Russian Chemical Bulletin

, Volume 45, Issue 5, pp 1200–1206 | Cite as

Reactions of 1,4-difeffocenylbuta-1,3-diyne and 1,4-diphenylbut-l-en-3-yne with Ru3(CO)12. Crystal structure of Ru3(CO)8(μ3-η-1-η1-η4-η2-C4Ph2(CH=CHPh)2)

  • A. A. Koridze
  • Y. I. Zdanovich
  • N. V. Andrievskaya
  • Yu. Siromakhova
  • P. V. Petrovskii
  • M. G. Ezernitskaya
  • F. M. Dolgushin
  • A. I. Yanovsky
  • Yu. T. Struchkov
Organometallic Chemistry
Received:

Abstract

Diyne FcCmCC.CFc (Fc is ferrocenyl) reacts with Ru3(CO)12 in boiling hexane to yield binuclear complexes Ru2 and Ru2(CO)6(C4Fc2(C=CFc)2C=O) containing ruthenacyclopentadiene and diruthenacycloheptadienone rings, respectively. The isomerism of the complexes is due to the different ways of coupling of the alkyne fragments of the diyne, namely, “head-to-head”, “head-to-tail” or “tail-to-tail”. The reaction of enyne PhC=CCH=CHPh with Ru3(CO)12 under similar conditions gives isomeric binuclear complexes Ru2(CO)6(C4Ph2(CH=CHPh)2) and trinuclear clusters Ru3(CO)6(w-CO)2(C4Ph2(CH=CHPh)2) and Ru3(CO)8(μ3-,η1-η1-η4-η2 C4Ph2(CH=CHPh)2). The structure of the latter was determined by X-ray diffraction analysis. The Ru3 triangle coordinates eight terminal CO groups and the organic ligand resulting from the “head-to-head” dimerization of enyne molecules; the ruthenacyclopentadiene moiety is η4-coordinated to the Ru(CO)2 group, and the third ruthenium atom is η2-bound to one of the PhCH=CH groups.

Key words

diynes enynes dimerization ruthenium clusters ruthenium carbonyls ruthenacycles 
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    W. B. Faklhammer and H. Stolzenberg, inComprehensive Organometallic Chemistry, Eds. G. Wilkinson, F. G. A. Stone, and E. Abel, Pergamon Press, Oxford, 1982, Ch. 31.4.Google Scholar
  2. 2.
    A. J. Deeming, M. S. B. Felix, and D. Nuel,Inorg. Chim. Acta, 1993,213, 3.Google Scholar
  3. 3.
    J. F. Corrigan, S. Doherty, N. J. Taylor, and A. J. Carty,Organometallics, 1993,12, 1365.Google Scholar
  4. 4.
    F. A. Cotton, J. D. Jamerson, and B. R. Stults,Inorg. Chim. Acta, 1976,17, 235.Google Scholar
  5. 5.
    A. A. Koridze, O. A.Kizas, N. E. Kolobova, N. V. Vinogradova, N. A. Ustynyuk, P. V. Petrovskii, A. I. Yanovsky, and Yu. T. Struchkov,J. Chem. Soc., Chem. Commun., 1984, 1158.Google Scholar
  6. 6.
    A. A. Koridze, O. A. Kizas, Yu. T. Struchkov, A. I. Yanovsky, and N. E. Kolobova,Metalloorg. Khim., 1988,1, 831 (Organomet. Chem. USSR, 1988,1, 460 (Engl. Transl.)].Google Scholar
  7. 7.
    O. A. Kizas, V. V. Krivykh, E. V. Vorontsov, and A. A. Koridze,Izv. Akad. Nauk, Ser. Khim., 1993, 1144 [Russ. Chem. Bull., 1993,42, 1102 (Engl. Transl.)].Google Scholar
  8. 8.
    A. A. Koridze, V. I. Zdanovich, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, and P. V. Petrovskii,Izv. Akad. Nauk, Ser. Khim., 1994, 2049 [Russ. Chem. Bull., 1994,43, 1938 (Engl. Transl.)].Google Scholar
  9. 9.
    A. A. Koridze, A. I. Yanovsky, and Yu. T. Struchkov,J. Organomet. Chem., 1992,441, 277.Google Scholar
  10. 10.
    S. Aime, R. Gobetto, G. Nicola, D. Osella, L. Milone, and F. Rosenberg,Organometallics, 1986,5, 1829.Google Scholar
  11. 11.
    A. A. Koridze and S. P. Gubin,J. Organomet. Chem., 1970,22, 157.Google Scholar
  12. 12.
    F. Rosenberg, S. Aime, L. Milone, E. Sappa, A. Tiripicchio, and A. M. Manotti hanfredi,J. Chem. Soc., Dalton Trans., 1981, 2023.Google Scholar
  13. 13.
    E. Sappa, A. M. Manotti Lanfredi, and A. Tiripicchio,Inorg. Chim. Acta, 1980,42, 255.Google Scholar
  14. 14.
    G. Ferraris and G. Gervasio,J. Chem. Soc., Dalton Trans., 1974, 1813.Google Scholar
  15. 15.
    D. Osella, G. Arman, R. Gobetto, F. Laschi, P. Zanello, S. Ayrtan, V. Goodfellow, C. F. Housecroft, and S. M. Owen,Organometallics, 1989,8, 2689.Google Scholar
  16. 16.
    F. Cabrera, J. C. Daran, J. Jeannin, and O. Kristiansson,J. Organomet. Chem., 1986,310, 367.Google Scholar
  17. 17.
    A. A. Koridze, N. M. Astakhova, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, and P. V. Petrovskii,Organometallics, 1995,14, 2167.Google Scholar
  18. 18.
    D. Osella, R. Gobetto, L. Milone, P. Zanello, and S. Mangani,Otganometallics, 1990,9, 2167.Google Scholar
  19. 19.
    K. Schlögl and H. Egger,Monatsh. Chem., 1963,94, 382.Google Scholar
  20. 20.
    J. Ohshita, K. Furumori, A. Matsugushi, and M. Ishikawa,J. Otg. Chem., 1990,55, 3277.Google Scholar

Copyright information

© Plenum Publishing Corporation 1996

Authors and Affiliations

  • A. A. Koridze
    • 1
  • Y. I. Zdanovich
    • 1
  • N. V. Andrievskaya
    • 1
  • Yu. Siromakhova
    • 1
  • P. V. Petrovskii
    • 1
  • M. G. Ezernitskaya
    • 1
  • F. M. Dolgushin
    • 1
  • A. I. Yanovsky
    • 1
  • Yu. T. Struchkov
    • 1
  1. 1.A. N. Nesmeyanpv Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations