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Colloid and Polymer Science

, Volume 264, Issue 3, pp 241–247 | Cite as

Polylaurylmethacrylate in bidimensional mixtures with low and high molecular weight substances: effect of the chain mobility on mutual miscibility

  • P. Baglioni
  • L. Dei
  • G. Gabrielli
Polymer Science

Abstract

Bidimensional two-component mixtures of polylaurylmethacrylate with polyoctadecylmethacrylate, polymethylmethacrylate and stearic acid were studied in the 15–30 °C temperature range at the air-water interface, in order to determine the effect of the “state” of the hydrophobic side chains on the bidimensional miscibility.

We showed that bidimensional miscibility depends on whether the two components have the same interfacial orientation, and that the “fluidity” of the polymer side chains also plays a very important role.

Key words

Monolayers air-water interface bidimensional mixtures polylaurylmethacrylate polyoctadecylmethacrylate polymethylmethacrylate stearic acid 

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References

  1. 1.
    Gabrielli G, Puggelli M, Baglioni P (1982) J Coll Interf Sci 86:485Google Scholar
  2. 2.
    Gabrielli G, Maddii A (1978) J Coll Interf Sci 64:19Google Scholar
  3. 3.
    Gabrielli G, Puggelli M, Faccioli R (1973) J Coll Interf Sci 44:177Google Scholar
  4. 4.
    Gabrielli G, Puggelli M, Ferroni E (1974) J Coll Interf Sci 47:145Google Scholar
  5. 5.
    Gabrielli G, Baglioni P, Maddii A (1981) J Coll Interf Sci 79:268Google Scholar
  6. 6.
    Baglioni P, Dei L, Puggelli M (1985) Coll & Polym Sci 263:266Google Scholar
  7. 7.
    Nakahara T, Motomura K, Matuura R (1967) Bull Chem Soc Japan 40:495Google Scholar
  8. 8.
    Yoshikawa S, Ueno M, Meguro K (1978) Coll & Polym Sci 256:422Google Scholar
  9. 9.
    Ueno M, Yoshikawa S, Meguro K (1979) J Coll Interf Sci 69:334Google Scholar
  10. 10.
    Nakahara T, Motomura K, Matuura R (1966) J Polym Sci A24:619Google Scholar
  11. 11.
    Yoshikawa S, Ueno M, Meguro K (1978) Bull Chem Soc Japan 51:3136Google Scholar
  12. 12.
    Brandrup J, Immergut EK (eds) (1975) Polymer Handbook, John Wiley and Sons, New York, pp III-147Google Scholar
  13. 13.
    Greenberg SA, Alfrey T (1954) J Amer Chem Soc 76:6280Google Scholar
  14. 14.
    Crisp DJ (1946) J Coll Sci 1:49; ibidem (1946) 1:161Google Scholar
  15. 15.
    Huggins ML (1973) Kolloid Z u Z Polym 251:449Google Scholar
  16. 16.
    Gaines Jr GL (1966) Insoluble Monolayers at Liquid-Gas Interfaces, Interscience, New York, pp 281–300Google Scholar
  17. 17.
    Shah DO, Shulman JH (1967) J Lipid Res 8:215PubMedGoogle Scholar

Copyright information

© Steinkopff 1986

Authors and Affiliations

  • P. Baglioni
    • 1
  • L. Dei
    • 1
  • G. Gabrielli
    • 1
  1. 1.Dipartimento di ChimicaUniversità degli Studi di FirenzeFirenzeItaly

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