Transition Metal Chemistry

, Volume 3, Issue 1, pp 215–217 | Cite as

Bis-η5-cyclopentadienyl and Bis-η5-methylcyclopentadienylN,N-dialkyldithiocarbamato(chloro)titanium(IV) compounds

  • Narender K. Kaushik
  • Bharat Bhushan
  • Gurdeep R. Chhatwal


Titanium(IV)N,N-dialkyldithiocarbamates of the type η5-Cp2Ti (S2CNR2)Cl and (η5-MeCp)2Ti(S2CNR2)Cl (R = Me, Et and i-Pr) have been prepared by the reaction of di--cyclopentadienyldichlorotitanium(IV) and bis-n-methylcyclopentadienyldichlorotitanium(IV) with sodium salts of dithiocarbamic acids in refluxing dichloromethane. Molecular weight, conductance and i.r. studies show these complexes to be monomeric nonelectrolytes in which the dithiocarbamate ligands are bidentate. Therefore, pentacoordination may be assigned to titanium(IV) atom in all six complexes. Electronic and proton n.m.r. studies spectra have also been recorded for the complexes.


Sodium Molecular Weight Titanium Physical Chemistry Inorganic Chemistry 
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Copyright information

© Springer-Verlag 1979

Authors and Affiliations

  • Narender K. Kaushik
    • 1
  • Bharat Bhushan
    • 1
  • Gurdeep R. Chhatwal
    • 1
  1. 1.Department of ChemistryUniversity of DelhiDelhiIndia

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