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Transition Metal Chemistry

, Volume 3, Issue 1, pp 215–217 | Cite as

Bis-η5-cyclopentadienyl and Bis-η5-methylcyclopentadienylN,N-dialkyldithiocarbamato(chloro)titanium(IV) compounds

  • Narender K. Kaushik
  • Bharat Bhushan
  • Gurdeep R. Chhatwal
Article

Summary

Titanium(IV)N,N-dialkyldithiocarbamates of the type η5-Cp2Ti (S2CNR2)Cl and (η5-MeCp)2Ti(S2CNR2)Cl (R = Me, Et and i-Pr) have been prepared by the reaction of di--cyclopentadienyldichlorotitanium(IV) and bis-n-methylcyclopentadienyldichlorotitanium(IV) with sodium salts of dithiocarbamic acids in refluxing dichloromethane. Molecular weight, conductance and i.r. studies show these complexes to be monomeric nonelectrolytes in which the dithiocarbamate ligands are bidentate. Therefore, pentacoordination may be assigned to titanium(IV) atom in all six complexes. Electronic and proton n.m.r. studies spectra have also been recorded for the complexes.

Keywords

Sodium Molecular Weight Titanium Physical Chemistry Inorganic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1979

Authors and Affiliations

  • Narender K. Kaushik
    • 1
  • Bharat Bhushan
    • 1
  • Gurdeep R. Chhatwal
    • 1
  1. 1.Department of ChemistryUniversity of DelhiDelhiIndia

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