Crystal and molecular structure oftrans-dichlorobis(oxazole)palladium(II)

  • E. Binamira-Soriaga
  • Munime Lundeen
  • Karl Seff
Article
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Abstract

The crystal and molecular structure oftrans-dichlorobis(oxazole)palladium-(II), Pd(C3H3ON)2Cl2, has been determined by single-crystal X-ray diffraction techniques using counter methods and has been refined by full-matrix least-squares procedures to a finalR index of 0.022. The complex crystallizes in the triclinic space groupP¯1 with unit cell dimensions ofa = 6.957(1),b = 7.506(1),c = 5.538(1) Å, α = 109.22(1), β = 91.37(1), and γ = 115.09(1) °, withZ = 1. The palladium(II) ion, located at an inversion center, is coordinated in a regular square-planar manner to two chloride ions at 2.293(1) Å and, at 2.016(2) Å, to the nitrogen atoms of two oxazole ligands. The planar oxazole rings are tilted 33 ° with respect to the PdN2Cl2 plane. Further verification of the presence of oxazole in the complex was obtained by high-resolution mass spectrometry. Crystals of Pd(C3H3ON)2Cl2 resulted irreproducibly from attempts to prepare single crystals of a previously reported dimeric palladium(II) disulfide complex by treating Pd(CH3CN)2Cl2 with a slight excess of diphenyl disulfide in benzene in the atmosphere. The source of the oxazole is not understood.

Keywords

Palladium Disulfide CH3CN Diphenyl Inversion Center 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • E. Binamira-Soriaga
    • 1
  • Munime Lundeen
    • 1
  • Karl Seff
    • 1
  1. 1.Chemistry DepartmentUniversity of Hawaii HonoluluHawaii

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