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Transition Metal Chemistry

, Volume 11, Issue 12, pp 463–464 | Cite as

Synthesis and characterisation of some new cyanonitrosyl chromium(l) complexes with phenetidines and anisidines

  • Ram C. Maurya
  • Dinesh C. Gupta
  • Rajesh Shukla
  • Raj K. Shukla
  • Nalmas Anandam
  • Mannar R. Maurya
Full Papers

Summary

A new series of cyano-substituted nitrosylchromium(I) complexes having octahedral stereochemistry around the metal ion, and of general formula, [CrNO(CN)2(L)2(H2O)] (L =o-,m- andp-phenetidines oro-,m-, andp-anisidines) have been isolated in the solid state by interaction of potassium pentacy-anonitrosylchromate(I) monohydrate with the appropriately substituted aniline. The complexes, which have been characterised by elemental analysis, conductance, molecular weight determination, magnetic measurements, e.s.r. and i.r. spectral studies, contain chromium(I) in a low-spin d5-configuration.

Keywords

Molecular Weight Potassium Physical Chemistry Chromium Inorganic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© VCH Verlagsgesellschaft mbH 1986

Authors and Affiliations

  • Ram C. Maurya
    • 1
  • Dinesh C. Gupta
    • 1
  • Rajesh Shukla
    • 1
  • Raj K. Shukla
    • 1
  • Nalmas Anandam
    • 1
  • Mannar R. Maurya
    • 2
  1. 1.Department of ChemistryAtarra P.G. CollegeAtarraIndia
  2. 2.Department of ChemistryRegional Engineering CollegeKurukshetra132119India

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