Hyperfine structure, mm wave rotational spectrum and molecular constants of the diatomic IF in its electronic ground stateX1 Σ+

  • J. Hoeft
  • K. P. R. Nair
Article

Abstract

At wavelengths near 1 mm the rotational transitionsJ=16←15 and 17←16 of the diatomic IF have been observed. The strong hyperfine transitions ΔF=+1 were measured in vibrational statesv=0, 1 and 2. The much weaker ΔF=0 components could be detected in the rotational transitionJ=17←16 of the molecule in its ground vibrational state. The analysis including previous measurements at larger wavelengths resulted in improved hyperfine parameters, an extended set of Dunham energy coefficients and potential constants.

PACS

33.20.Bx 

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References

  1. 1.
    Durie, R.A.: Can. J. Phys.44, 337 (1966)Google Scholar
  2. 2.
    Birks, J.W., Gabelnick, S.D., Johnston, H.S.: J. Mol. Spectry.57, 23 (1975)Google Scholar
  3. 3.
    Clyne, M.A.A., Coxon, J.A., Townsend, L.W.: J. Chem. Soc. Faraday Trans. II,68, 2134 (1972)Google Scholar
  4. 4.
    Clyne, M.A.A., McDermid, I.S.: J. Chem. Soc. Faraday Trans. II,72, 2252 (1976)Google Scholar
  5. 5.
    Tiemann, E., Hoeft, J., Törring, T.: Z. Naturforsch.28a, 1405 (1973)Google Scholar
  6. 6.
    McGurk, J.C., Flygare, W.H.: J. Chem. Phys.59, 5742 (1973)Google Scholar
  7. 7.
    Nair, K.P.R., Hoeft, J., Tiemann, E.: Chem. Phys. Lett.60, 253 (1979)Google Scholar
  8. 8.
    Coxon, J.A.: J. Chem. Soc. Faraday Trans.: II.:74, 1664 (1978)Google Scholar
  9. 9.
    Trickl, T., Wanner, J.: J. Mol. Spectry.104, 174 (1984)Google Scholar
  10. 10.
    Hartmann, H.D., Knöckel, H., Tiemann, E.: Chem. Phys. Lett.113, 364 (1985)Google Scholar
  11. 11.
    Nair, K.P.R., Hoeft, J.: Phys. Rev. A35, 668 (1987)Google Scholar
  12. 12.
    Hoeft, J., Nair, K.P.R.: Z. Phys. D — Atoms, Molecules and Clusters4, 189 (1986)Google Scholar
  13. 13.
    Townes, C.H., Schawlow, A.L.: Microwave spectroscopy. New York, McGraw-Hill 1955Google Scholar
  14. 14.
    Dunham, J.L.: Phys. Rev.41, 721 (1932)Google Scholar
  15. 15.
    Cohen, E.R., Taylor, B.N.: J. Phys. Chem. Ref. Data2, 717 (1973)Google Scholar
  16. 16.
    Wapstra, A.H., Bos, K.: At. Data Nucl. Data Tables19, 177 (1977)Google Scholar

Copyright information

© Springer-Verlag 1988

Authors and Affiliations

  • J. Hoeft
    • 1
  • K. P. R. Nair
    • 1
  1. 1.Institut für Molekülphysik der Freien Universität BerlinBerlin 33Germany

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