Hyperfine structure, mm wave rotational spectrum and molecular constants of the diatomic IF in its electronic ground stateX1 Σ+
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Abstract
At wavelengths near 1 mm the rotational transitionsJ=16←15 and 17←16 of the diatomic IF have been observed. The strong hyperfine transitions ΔF=+1 were measured in vibrational statesv=0, 1 and 2. The much weaker ΔF=0 components could be detected in the rotational transitionJ=17←16 of the molecule in its ground vibrational state. The analysis including previous measurements at larger wavelengths resulted in improved hyperfine parameters, an extended set of Dunham energy coefficients and potential constants.
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