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Zeitschrift für Physik A Hadrons and nuclei

, Volume 192, Issue 4, pp 329–339 | Cite as

Die Frequenzabhängigkeit des rotatorischen und translatorischen Anteils der kernmagnetischen Relaxation in Flüssigkeiten

  • H. E. Heinze
  • H. Pfeifer
Article

Abstract

A separation into intra- and intermolecular contributions of nuclear magnetic relaxation rates is necessary for an unambiguous interpretation of experimental results. The wellknown method of dilution with deuterated molecules in the case of proton relaxation however is not applicable to systems with fast intermolecular proton exchange. The necessary conditions are proved for a separation of the two contributions from the frequency dependence of relaxation rates.

Errors resulting from a neglect of small inter- or intramolecular contributions are discussed.

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Copyright information

© Springer-Verlag 1966

Authors and Affiliations

  • H. E. Heinze
    • 1
  • H. Pfeifer
    • 1
  1. 1.Physikalisches Institut der Karl-Marx-Universität LeipzigDeutschland

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