High temperature superconductivity research at the IBM thomas J. Watson and Almaden research centers
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Abstract
Complementing the work of Bednorz and Müller, which started the field of high temperature oxide superconductivity, the IBM Research laboratories at Yorktown Heights in Almaden have made contributions also via many outside collaborations across the full scope of this field. Materials work includes the identification, separation and structural characterization of the YBa2Cu3O7−x phase, the detection of superconductivity and antiferromagnetism in La2CuO4, and the deposition of YBaCuO films with transition temperatures above 77 K by electron-beam deposition and plasma spraying. Characterization work includes measurement of the superconducting energy gap by far-infrared and tunneling measurements, study of Meissner and diamagnetic shielding, observation of superconducting fluctuations, correlation of [Cu−O]+ complex concentration withTc, and determination of valence electronic structure by photoemission. Theoretical work includes proposal of an interband scattering mechanism for superconductivity, a mean-field solution to an electron-interaction model, band-structure calculations, and a phenomenological model for lattice parameters and their influence onTc. YBa2CU3O7−d single crystals have been synthesized and shown to exhibit up to 70:1 magnetic anisotropy. In work of relevance to applications, the first thin film SQUIDs have been operated in temperatures up to 68 K, epitaxial films on SrTiO3 have been found to sustain critical currents of more than 105 A/cm2 at 77 K, and coatings, superconducting above 77 K, have been deposited by plasma spraying.
Keywords
Magnetic Anisotropy High Temperature Superconductivity High Temperature Oxide Epitaxial Film La2CuO4Preview
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References
- 1.Bednorz, J.G., Müller, K.A.: Possible HighT c Superconductivity in the Ba−La−Cu−O System. Z. Phys. B-Condensed Matter64, 189 (1986)Google Scholar
- 2.Bednorz, J.G., Takashige, M., Müller, K.A.: Susceptibility Measurements Support HighT c in the Ba−La−Cu−O System. Europhys. Lett.3, 379 (1987)Google Scholar
- 3.Müller, K.A., Takashige, M., Bednorz, J.G.: Flux Trapping and Superconductive Glass State in La2CuO4−yBa. Phys. Rev. Lett.58, 1143 (1987)Google Scholar
- 4.Bednorz, J.G., Müller, K.A., Takashige, M.: Superconductivity in Alkaline-Earth Substituted La2CuO4−y Science236, 73 (1987)Google Scholar
- 5.Bednorz, J.G., Takashige, M., Müller, K.A.: Preparation and Characterization of Alkaline-Earth Substituted Superconducting La2CuO4. Mater. Res. Bull. (submitted for publication)Google Scholar
- 6.Schlesinger, Z., Greene, R.L., Bednorz, J.G., Müller, K.A.: Far-Infrared Measurement of the Energy Gap of La1.8Sr0.2CuO4. Phys. Rev. B35, 5334 (1987)Google Scholar
- 7.Maletta, H., Malozemoff, A.P., Cronemeyer, D.C., Tsuei, C.C., Greene, R.L., Bednorz, J.G., Müller, K.A.: Diamagnetic Shielding and Meissner Effect in the HighT c Superconductor Sr0.2La1.8CuO4. Solid State Commun.62, 323 (1987)Google Scholar
- 8.Lee, D.H., Ihm, J.: Two-Band Model for HighT c Superconductivity in La2−x(Ba, Sr)xCuO4. Solid State Commun. (accepted for publication)Google Scholar
- 9.Kirtley, J.R., Tsuei, C.C., Park, Sung I., Chi, C.C., Rozen, J., Shafer, M.W.: Local Tunneling Measurements of the HighT c Superconductor La2−xSrxCuO4−y. Phys. Rev. B135, 7216 (1987)Google Scholar
- 10.Malozemoff, A.P.: Simple Model for Lattice Parameters andT c of Superconductors with the K2NiF4 Structure. Mater. Res. Bull. (accepted for publication)Google Scholar
- 11.Grant, P.M., Beyers, R.B., Engler, E.M., Lim, G., Parkin, S.S.P., Ramirez, M.L., Lee, V.Y., Nazzal, A., Vazquez, J.E., Savoy, R.J.: Superconductivity Above 90 K in the Compound YBa2Cu3Ox: Structural, Transport and Magnetic Properties. Phys. Rev. B135, 7242 (1987)Google Scholar
- 12.Gallagher, W., Sandstrom, R.L., Dinger, T., Shaw, T.M., Chance, D.: Identification and Preparation of Single Phase 90 K Oxide Superconductor and Structural Determination by Lattice Imaging. Solid State Commun. (submitted for publication)Google Scholar
- 13.Kirtley, J.R., Gallagher, W.J., Schlesinger, Z., Sandstrom, R.L., Dinger, T.R., Chance, D.A.: Tunneling and Infra-red Measurements of the Energy Gap in the High Critical Temperature Superconductor Y−Ba−CuO. Phys. Rev. B (Rapid Commun.) (submitted for publication)Google Scholar
- 14.Laibowitz, R.B., Koch, R.H., Chaudhari, P., Gambino, R.J.: Thin Superconducting Oxide Films. Phys. Rev. B135 (June 1987)Google Scholar
- 15.Schlesinger, Z., Collins, R.T., Shafer, M.W.: Observation of a Low Energy Infrared Anomaly in Superconducting La1.85Sr0.15CuO4. Phys. Rev. B135, 7232 (1987)Google Scholar
- 16.Beyers, R., Lim, G., Engler, E.M., Savoy, R.J., Shaw, T.M., Dinger, T.R., Gallagher, W.J., Sandstrom, R.L.: Crystallography and Microstructure of Y1Ba2Cu3O9−x. A Perovskite-Based Superconducting Oxide. Appl. Phys. Lett. (submitted for publication)Google Scholar
- 17.Burns, G., Dacol, F.H., Shafer, M.W.: Raman Measurement of Materials with the K2NiF4 Structure. Solid State Commun. (to be published)Google Scholar
- 18.Engler, E.M., Lee, V.Y., Nazzal, A.I., Beyers, R.B., Lim, G., Grant, P.M., Parkin, S.S.P., Ramirez, M.L., Vazquez, J.E., Savoy, R.J.: Superconductivity above Liquid Nitrogen Temperature: Preparation and Properties of a Family of Perovskite-Based Superconductors. J. Am. Chem. Soc. (submitted for publication)Google Scholar
- 19.Greene, R.L., Maletta, H., Plaskett, T.S., Bednorz, J.G., Müller, K.A.: Evidence for Electron-Electron Correlations in La2CuO4 and La2−xSrxCuO4 Superconductors. Solid State Commun. (to be published)Google Scholar
- 20.Frase, K.G., Liniger, E.G., Clarke, D.R.: Phase Compatibilities in the System Y2O3−BaO−CuO at 950°C. Commun. Am. Ceramic Soc. (submitted for publication)Google Scholar
- 21.Kasowski, R., Hsu, W., Herman, F.: Electronic Structure of Pure and Doped Orthorhombic La2CuO4. Solid State Commun. (to be published)Google Scholar
- 22.Clark, G.J., Marwick, A.D., Koch, R.H., Laibowitz, R.B.: Effects of Radiation Damage in Ion-Implanted Thin Films of Metal Oxide Superconductors. Appl. Phys. Lett. (submitted for publication)Google Scholar
- 23.Freitas, P.P., Tsuei, C.C., Plaskett, T.S.: Thermodynamic Fluctuations in the Y1Ba2Cu3O9−d Superconductor: Evidence for 3D Superconductivity. Phys. Rev. B (Rapid Commun.) (to be published)Google Scholar
- 24.Grant, P.M., Parkin, S.S.P., Green, R.L., Lee, V.Y., Engler, E.M., Ramirez, M.L., Vazques, J.E., Lim, G., Jacowitz, R.D.: Evidence for Superconductivity in La2CuO4. Phys. Rev. Lett. (June 8, 1987)Google Scholar
- 25.Koch, R.H., Umbach, C.P., Clark, G.J., Chaudhari, P., Laibowitz, R.B.: Quantum Interference Devices (SQUIDs) Made from Superconducting Oxide Thin Films. App. Phys. Lett. (to be published)Google Scholar
- 26.Dinger, T.R., Worthington, T.K., Gallagher, W.J., Sandstrom, R.L.: Direct Observation of Electronic Anisotropy in Single-Crystal Y1Ba2Cu3O7−x. Phys. Rev. Lett. (submitted for publication)Google Scholar
- 27.Chaudhari, P., Koch, R.H., Laibowitz, R.B., McGuire, T.R., Gambino, R.J.: Critical Current Measurements in Epitaxial Films of YBa2Cu3O7−x. Phys. Rev. Lett. (submitted for publication)Google Scholar
- 28.Newns, D.M.: Mean Field Solution to the Electron-Interaction Model of Oxide Superconductivity. Phys. Rev. B (submitted for publication)Google Scholar
- 29.Beyers, R., Lim, G., Engler, E.M., Lee, V.Y., Ramirez, M.L., Savoy, R.J., Jacowitz, R.D., Shaw, T.M., LaPlaca, S., Boehme, R., Tsuei, C.C., Park, S.I., Shafer, M.W., Gallagher, W.J., Chandrashekhar, G.V.: Annealing Treatment Effects on Structure and Superconductivity in Y1Ba2Cu3O9−x. Appl. Phys. Lett. (submitted for publication)Google Scholar
- 30.Yarmoff, J.A., Clarke, D.R., Drube, W., Karlsson, U.O., Taleb-Ibrahimi, A., Himpsel, F.J.: Valence Electronic Structure of Y1Ba2Cu2O7. (submitted for publication)Google Scholar
- 31.Schrott, A.G., Park, S.I., Tsuei, C.C.: Effect of Oxygen Deficiency on HighT c Superconductivity: A Photoemission Study of YBa2Cu3O7. (submitted for publication)Google Scholar
- 32.Maletta, H., Greene, R.L., Plaskett, T.S., Bednorz, J.G., Müller, K.A.: Evidence for Electron-Electron Correlations in Pure and Sr-doped La2CuO4. Proc. LT 18 (submitted for publication)Google Scholar
- 33.Kirtley, J.R., Tsuei, C.C., Park, S.I., Chi, C.C., Rozen, J., Shafer, M.W., Gallagher, W.J., Sandstrom, R.L., Dinger, T.R., Chance, D.A.: Tunneling Measurements of the Energy Gap in HighT c Oxide Superconductors. Proc. LT 18 (submitted for publication)Google Scholar
- 34.Shafer, M.W., Penney, T., Olson, B.L.: Correlation of Superconducting Transition Temperature with Hole Concentration in La2−xSrxCuO4−d. Phys. Rev. B (submitted for publication)Google Scholar
- 35.Collins, R., Schlesinger, Z., Chaudhari, P., Koch, R.H., Laibowitz, R.B., Gambino, R.J.: Far Infrared Measurements of Epitaxial YBa2Cu3O7−x Films. (manuscript in preparation)Google Scholar
- 36.Dinger, T.R., Cook, R.F., Clarke, D.R.: Fracture Toughness of YBa2Cu3O7−x Single Crystals. Appl. Phys. Lett. (submitted for publication)Google Scholar
- 37.Cuomo, J.J., Guarnieri, C.R., Shivashankar, S.A., Roy, R.A., Yee, D.S., Rosenberg, R.: Large Area Plasma Deposited Superconducting YBaCuO Thick Films. Appl. Phys. Lett. (submitted for publication)Google Scholar
- 38.Kasowki, R., Hsu, W., Herman, F.: (submitted for publication)Google Scholar
- 39.Chu, C.W., Hor, P.H., Meng, R.L., Gao, L., Huang, Z.J., Wang, Y.Q.: Phys. Rev. Lett.58, 405 (1987)Google Scholar
- 40.Suhl, H., Matthias, B.T., Walker, L.R.: Phys. Rev. Lett.12, 552 (1959)Google Scholar
- 41.Jorgensen, J.D., Shuttler, H.-B., Hinks, D.G., Capone II, D.W., Zhang, K., Brodsky, M.B., Scalapino, D.J.: Phys. Rev. Lett.58, 1024 (1987); Mattheiss, L.F.: Phys. Rev. Lett.58, 1028 (1987); Yu, J., Freemann, A.J., Xu, J.-H.: Phys. Rev. Lett.58, 1035 (1987)Google Scholar
- 42.Hirsch, J.E.: Phys. Rev. Lett.54, 1317 (1985)Google Scholar
- 43.Anderson, P.W.: Science235, 1196 (1987)Google Scholar
- 44.Wu, M.K., Ashburn, J.R., Torng, C.J., Hor, P.H., Meng, R.L., Gao, L., Huang, Z.J., Wang, Y.Q., Chu, C.W.: Phys. Rev. Lett.58, 908 (1987)Google Scholar
- 45.Zhao, Z., Chen, L., Yang, Q., Huang, Y., Chen, G., Tang, R., Liu, G., Ni, Y., Cui, C., Chen, L., Wang, L., Guo, S., Li, S., Bi, J.: KeXue Tongbao (China) (to be published)Google Scholar
- 46.Mattheiss, L.F., Hamann, D.R.: Phys. Rev. Lett. (to be published)Google Scholar
- 47.Zeller, H.R., Giaever, I.: Phys. Rev.181, 798 (1969)Google Scholar
- 48.Tinkham, M.: Introduction to Superconductivity. New York: McGraw-Hill 1975Google Scholar
- 49.Lee, Ihm: Solid State Commun. (1987)Google Scholar