Zeitschrift für Physik B Condensed Matter

, Volume 61, Issue 4, pp 439–445 | Cite as

Geometry and bond lengths of chemisorbed atoms and molecules: NEXAFS and SEXAFS

  • J. Stöhr
Article

Abstract

A brief review is given of the near edge x-ray absorption fine structure (NEXAFS) and surface extended x-ray absorption fine structure (SEXAFS) techniques which have been developed in conjunction with the availability of high brightness monochromatic synchrotron radiation. Concepts and applications of the techniques are discussed using selected examples of chemisorption problems involving atoms and molecules on surfaces. Extensive references to related work are given.

Keywords

Radiation Spectroscopy Neural Network Bond Length Complex System 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Stöhr, J., Jaeger, R.: Phys. Rev. B26, 4111 (1982)Google Scholar
  2. 2.
    Citrin, P.H., Eisenberger, P., Hewitt, R.C.: Phys. Rev. Lett.41, 309 (1978)Google Scholar
  3. 3a.
    Stöhr, J., Denley, D., Perfetti, P.: Phys. Rev. B18, 4132 (1978)Google Scholar
  4. 3b.
    Stöhr, J.: Jpn. J. Appl. Phys.17, Suppl. 17–2, 217 (1978)Google Scholar
  5. 4a.
    Bianconi, A.: Appl. Surf. Sci.6, 392 (1980)Google Scholar
  6. 4b.
    Natoli, C.R.: EXAFS and Near Edge Structure. In: Springer Series in Chemical Physics. Bianconi, A., Incoccia, L., Stipich, S. (eds.), Vol. 27, p. 43. Berlin, Heidelberg, New York: Springer 1982Google Scholar
  7. 4c.
    Durham, P.J., Pendry, J.B., Hodges, C.H.: Comput. Phys. Commun.25, 193 (1982)Google Scholar
  8. 5.a)
    For reviews of EXAFS spectroscopy see: Stern, E.A.: Contemp. Phys.19, 289 (1978)Google Scholar
  9. 5.b)
    Eisenberger, P., Kincaid, B.M.: Science200, 1441 (1978)Google Scholar
  10. 5.c)
    Sandstrom, D.R., Lytle, F.W.: Annu. Rev. Phys. Chem.30, 215 (1979)Google Scholar
  11. 5d.)
    Rabe, P., Haensel, R.: In: Festkörperprobleme 20. p. 43. Stuttgart: Pergamon-Vieweg 1980Google Scholar
  12. 5e.)
    Lee, P.A., Citrin, P.H., Eisenberger, P., Kincaid, B.M.: Rev. Mod. Phys.53, 769 (1981)Google Scholar
  13. 5f.)
    EXAFS Spectroscopy, Techniques and Applications. Teo, B.K., Joy, D.C. (eds.). New York: Plenum Press 1981Google Scholar
  14. 5g.)
    Principles, Applications, Techniques of EXAFS, SEXAFS and XANES. Prins, R., Koningsberger, D. (eds.). New York: Wiley 1985Google Scholar
  15. 6.
    For a review see: Stöhr, J., Noguera, C., Kendelewicz, T.: Phys. Rev. B30, 5571 (1984)Google Scholar
  16. 7.
    Sayers, D.E., Lytle, F.W., Stern, E.A.: Phys. Rev. Lett.27, 1204 (1971)Google Scholar
  17. 8a.
    Citrin, P.H., Eisenberger, P., Hewitt, R.C.: Phys. Rev. Lett.45, 1948 (1980)Google Scholar
  18. 8b.
    Citrin, P.H., Hamann, D.R., Mattheiss, L.F., Rowe, J.E.: Phys. Rev. Lett.49, 1712 (1982)Google Scholar
  19. 8c.
    Comin, F., Citrin, P.H., Eisenberger, P., Rowe, J.E.: Phys. Rev. B26, 7060 (1982)Google Scholar
  20. 9a.
    Johannson, L.I., Stöhr, J.: Phys. Rev. Lett.43, 1882 (1979)Google Scholar
  21. 9b.
    Brennan, S., Stöhr, J., Jaeger, R.: Phys. Rev. B24, 4871 (1981)Google Scholar
  22. 9c.
    Stöhr, J., Jaeger, R., Kendelewicz, T.: Phys. Rev. Lett.49, 142 (1982)Google Scholar
  23. 10a.
    Döbler, U., Baberschke, K., Haase, J., Puschmann, A.: Phys. Rev. Lett.52, 1437 (1984)Google Scholar
  24. 10b.
    Puschmann, A., Haase, J.: Surf. Sci.144, 559 (1984)Google Scholar
  25. 10c.
    Döbler, U., Baberschke, K., Stöhr, J., Outka, D.A.: Phys. Rev. B31, 2532 (1985)Google Scholar
  26. 11a.
    Stöhr, J., Johansson, L., Lindau, I., Pianetta, P.: Phys. Rev. B20, 664 (1979)Google Scholar
  27. 10b.
    Stöhr, J., Bauer, R.S., McMenamin, J.C., Johansson, L., Brennan, S.: J. Vac. Sci. Technol.16, 1195 (1979)Google Scholar
  28. 12.
    Citrin, P.H., Eisenberger, P., Rowe, J.E.: Phys. Rev. Lett.48, 802 (1982)Google Scholar
  29. 13.
    Citrin, P.H., Rowe, J.E., Eisenberger, P.: Phys. Rev. B28, 2299 (1983)Google Scholar
  30. 14.a)
    Stöhr, J., Outka, D.A., Madix, R.J., Döbler, U.: Phys. Rev. Lett.54, 1256 (1985)Google Scholar
  31. 14.b)
    Outka, D.A., Madix, R.J., Stöhr, J.: Surf. Sci. (to be published)Google Scholar
  32. 14.c)
    Puschmann, A., Haase, J., Crapper, M.D., Riley, C.E., Woodruff, D.P.: Phys. Rev. Lett.54, 2250 (1985)Google Scholar
  33. 15a.
    Stöhr, J., Jaeger, R.: J. Vac. Sci. Technol.21, 619 (1982)Google Scholar
  34. 15b.
    Rossi, G., Jaeger, R., Stöhr, J., Kendelewicz, T., Lindau, I.: Phys. Rev. B27, 5154 (1983)Google Scholar
  35. 15c.
    Stöhr, J., Jaeger, R., Rossi, G., Kendelewicz, T., Lindau, I.: Surf. Sci.134, 813 (1983)Google Scholar
  36. 16.
    Comin, F., Rowe, J.E., Citrin, P.H.: Phys. Rev. Lett.51, 2402 (1983)Google Scholar
  37. 17.
    Comin, F., Incoccia, L., Lagarde, P., Rossi, G., Citrin, P.H.: Phys. Rev. Lett.54, 122 (1985)Google Scholar
  38. 18a.)
    For reviews of SEXAFS spectroscopy see: Stöhr, J.: In: Emission and Scattering Techniques. Day, P. (ed.). Dordrecht: Reidel 1981Google Scholar
  39. 18.b)
    Stöhr, J., Jaeger, R., Brennan, S.: Surf. Sci.117, 503 (1982)Google Scholar
  40. 18.c)
    Stöhr, J.: Chemistry and Physics of Solid Surfaces. In: Springer Series in Chemical Physics 35. Vanselow, V.R., Howe, R. (eds.), Vol. 5, p. 231. Berlin, Heidelberg, New York: Springer-Verlag 1984Google Scholar
  41. 18d.)
    Stöhr, J.: In: Principles, Applications, Techniques of EXAFS, SEXAFS and XANES. Prins, R., Koningsberger, D. (eds.). New York: Wiley 1985Google Scholar
  42. 19a.
    Dill, D., Dehmer, J.L.: J. Chem. Phys.61, 692 (1974)Google Scholar
  43. 19b.
    Dehmer, J.L., Dill, D.: J. Chem. Phys.65, 5327 (1976)Google Scholar
  44. 20.
    Natoli, C.R., Misemer, D.K., Doniach, S., Kutzler, F.W.: Phys. Rev. A22, 1104 (1980)Google Scholar
  45. 21.
    Bianconi, A., Del'Ariccia, M., Durham, P.J., Pendry, J.B.: Phys. Rev. B26, 6502 (1982)Google Scholar
  46. 22.
    Greaves, G.N., Durham, P.J., Diakun, G., Quinn, P.: Nature294, 139 (1981)Google Scholar
  47. 23.
    Gaskell, P.H., Glover, D.M., Livesey, A.K., Durham, P.J., Greaves, G.N.: J. Phys. C-Solid State Phys.15, L 597 (1982)Google Scholar
  48. 24.
    Norman, D., Stöhr, J., Jaeger, R., Durham, P.J., Pendry, J.B.: Phys. Rev. Lett.51, 2052 (1983)Google Scholar
  49. 25.
    Horsley, J.A., Stöhr, J., Koestner, R.J.: J. Chem. Phys. (to be published)Google Scholar
  50. 26.
    Stöhr, J., Baberschke, K., Jaeger, R., Treichler, T., Brennan, S.: Phys. Rev. Lett.47, 381 (1981)Google Scholar
  51. 27.
    For a review see: Sette, F., Stöhr, J.: EXAFS and Near Edge Structure III. In: Springer Proceedings in Physics. Hodgson, K.O., Hedman, B., Penner-Hahn, J.E. (eds.), Vol. 2, p. 250. Berlin, Heidelberg, New York: Springer-Verlag 1985Google Scholar
  52. 28.
    Boon-Keng Teo, Lee, P.A.: J. Am. Chem. Soc.99, 3854 (1977)Google Scholar
  53. 29a.
    Thiel, W.: J. Electron Spectrosc.31, 151 (1983)Google Scholar
  54. 29b.
    Kreile, J., Schweig, A., Thiel, W.: Chem. Phys. Lett.108, 259 (1984)Google Scholar
  55. 30.
    Johnson, A.L., Muetterties, E.L., Stöhr, J.: J. Am. Chem. Soc.105, 7183 (1983)Google Scholar
  56. 31.
    Koestner, R.J., Stöhr, J., Gland, J.L., Horsley, J.: Chem. Phys. Lett.105, 332 (1984)Google Scholar
  57. 32.
    Carr, R.G., Sham, T.K., Eberhardt, W.: Chem. Phys. Lett.113, 63 (1985)Google Scholar
  58. 33.
    Koestner, R.J., Stöhr, J., Gland, J.L., Kollin, E.B., Sette, F.: Chem. Phys. Lett. (to be published)Google Scholar
  59. 34.
    Hitchcock, A.P., Beaulieu, S., Steel, T., Stöhr, J., Sette, F.: J. Chem. Phys.80, 3927 (1984)Google Scholar
  60. 35.
    Sette, F., Stöhr, J., Hitchcock, A.P.: Chem. Phys. Lett.110, 517 (1984); J. Chem. Phys.81, 4906 (1984)Google Scholar
  61. 36.
    Stöhr, J., Gland, J.L., Eberhardt, W., Outka, D., Madix, R.J., Sette, F., Koestner, R.J., Döbler, U.: Phys. Rev. Lett.51, 2414 (1983)Google Scholar
  62. 37.
    Stöhr, J., Sette, F., Johnson, A.L.: Phys. Rev. Lett.53, 1684 (1984)Google Scholar
  63. 38.
    Sette, F., Stöhr, J., Kollin, E.B., Dwyer, D.J., Gland, J.L., Robbins, J.L., Johnson, A.L.: Phys. Rev. Lett.54, 935 (1985)Google Scholar
  64. 39.
    Horsley, J.A., Stöhr, J., Hitchcock, A.P., Newbury, D.C., Johnson, A.L., Sette, F.: J. Chem. Phys. (to be published)Google Scholar
  65. 40.
    Johnson, A.L., Muetterties, E.L., Stöhr, J., Sette, F.: (to be published)Google Scholar
  66. 41.
    Johnson, A.L., Muetterties, E.L., Stöhr, J., Sette, F. J. Phys. Chem. (to be published)Google Scholar
  67. 42.
    Stöhr, J., Gland, J.L., Kollin, E.B., Koestner, R.J., Johnson, A.L., Muetterties, E.L., Sette, F.: Phys. Rev. Lett.53, 2161 (1984)Google Scholar
  68. 43a.
    Stöhr, J.: Jpn. J. Appl. Phys.17, Suppl. 17–2, 217 (1978)Google Scholar
  69. 43b.
    Stöhr, J., Johansson, L., Lindau, I., Pianetta, P.: Phys. Rev. B20, 664 (1979)Google Scholar
  70. 44.
    Jaeger, R., Feldhaus, J., Haase, J., Stöhr, J., Hussain, Z., Menzel, D., Norman, D.: Phys. Rev. Lett.45, 1870 (1981)Google Scholar
  71. 45.
    For a review see: Desorption induced by electronic transitions. In: Springer Series in Chemical Physics. Vol. 24. Berlin, Heidelberg, New York: Springer-Verlag 1983Google Scholar
  72. 46.
    Jaeger, R., Stöhr, J., Kendelewicz, T.: Surf. Sci.134, 547 (1983)Google Scholar
  73. 47.
    Jaklevic, J., Kirby, J.A., Klein, M.P., Robertson, A.S., Brown, G.S., Eisenberger, P.: Solid State Commun.23, 679 (1977)Google Scholar
  74. 48.
    Hastings, J.B.: In: EXAFS Spectroscopy. Techniques and Applications. Teo, B.K., Joy, D.C. (eds.) New York, London: Plenum Press 1981Google Scholar
  75. 49.
    Heald, S.M., Keller, E., Stern, E.A.: Phys. Lett.103A, 155 (1984)Google Scholar
  76. 50.
    Krause, M.O.: J. Phys. Chem. Ref. Data8, 307 (1979)Google Scholar
  77. 51.
    Stöhr, J., Kollin, E.B., Fischer, D.A., Hastings, J.B., Zaera, F., Sette, F.: Phys. Rev. Lett. (to be published)Google Scholar

Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • J. Stöhr
    • 1
  1. 1.IBM Research LaboratorySan JoseUSA

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