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Microchimica Acta

, Volume 126, Issue 1–2, pp 153–157 | Cite as

Simultaneous determination of tartrazine and sunset yellow in cosmetic products by first-derivative spectrophotometry

  • Luis Fermín Capitán-Vallvey
  • Natalia Navas Iglesias
  • Ignacio de Orbe Payá
  • Ramiro Avidad Castaneda
Original Papers

Abstract

A spectrophotometric method for the simultaneous determination of Tartrazine (TT) and Sunset Yellow (SY) in cosmetic products has been developed. An extraction process was carried out using methylene chloride and the colouring matters were measured in the aqueous phase formed, the other components of the sample remaining in the organic phase. The applicable concentration ranges were 0.5–10 ug/ml TT and 0.5–12 μg/ml SY. The detection limits were 26 and 11 ng/ml and the relative standard deviations were 1.0 and 0.9% for TT and SY, respectively. The method was applied to the determination of both compounds in cosmetics.

Key words

first-derivative Spectrophotometry cosmetics Tartrazine-Sunset Yellow mixture determination 

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References

  1. [1]
    H. Sasaki,Tottori Daigaku Kogakubu Kenyu Hokoku 1978,9, 105.Google Scholar
  2. [2]
    H. Sasaki,Shokuhim Eisegaku Zasshi 1979,20, 93.Google Scholar
  3. [3]
    H. Zeng, C. Fan,Shipin yu Fajiao Gongye 1984,2, 35.Google Scholar
  4. [4]
    E. Momosaki, T. Fujimoyo,Fukuoka-shi Eisei Shikenshoho 1987,12, 53.Google Scholar
  5. [5]
    F. Salinas, J. J. Berzas, A. EspinosaTalanta 1990,37, 347.Google Scholar
  6. [6]
    J. J. Berzas, J. Rodriguez, M. J. Villasenor,Talanta 1993,40, 1391.Google Scholar
  7. [7]
    J. J. Berzes, J. Rodriguez, M. J. Villasenor,Bull. Soc. Chim. Belg. 1993,102, 527.Google Scholar
  8. [8]
    J. J. Berzas, J. Rodriguez, M. J. Villaseñor,Anal. Lett. 1994,27, 1009.Google Scholar
  9. [9]
    A. A. Barros,Analyst 1987,112, 1359.Google Scholar
  10. [10]
    A. G. Fogg, D. Bhanot,Analyst 1987,112, 1319.Google Scholar
  11. [11]
    A. G. Fogg, D. Bhanot, J. O. Cabrai,Analyst 1986,111, 813.Google Scholar
  12. [12]
    Statgraphics V. 6.0, Manugistics Inc and Statistical Graphics Corporation, USA, 1992.Google Scholar
  13. [13]
    A. Senzel (ed.),Newburger's Manual of Cosmetic Analysis, 2nd Ed., The Association of Official Analytical Chemists, Washington, 1977, p. 120.Google Scholar
  14. [14]
    B. Morelli,Analyst 1983,108, 870.Google Scholar
  15. [15]
    B. Morelli,Analyst 1988,113, 1077.Google Scholar
  16. [16]
    A. Savitzky, M. J. E. Golay,Anal. Chem. 1964,36, 1627.Google Scholar
  17. [17]
    J. Steiner, Y. Termonia, J. Deltour,Anal. Chem. 1972,44, 1906.Google Scholar
  18. [18]
    J. Holló, A. Wieg, YearbookInst. Agr. Chem. Technol. Univ. Tech. Sci., Budapest, 1952, III and 1954, II.Google Scholar
  19. [19]
    Analytical Methods Committee, Analytical Division, The Royal Society of Chemistry,Analyst 1994,119, 2363.Google Scholar
  20. [20]
    Nomenclature, Symbols, Units and Their Usage in Spectrochemical Analysis II,Spectrochim. Acta (B) 1978,33B, 242.Google Scholar
  21. [21]
    Analytical Methods Committee: Recommendations for the Definition, Estimation and Use of the Detection Limits,Analyst 1988,113, 1469.Google Scholar
  22. [22]
    Guidelines for Data Acquisition and Data Quality Evaluation in Environmental Analysis,Anal. Chem. 1980,52, 2242.Google Scholar

Copyright information

© Springer-Verlag 1997

Authors and Affiliations

  • Luis Fermín Capitán-Vallvey
    • 1
  • Natalia Navas Iglesias
    • 1
  • Ignacio de Orbe Payá
    • 1
  • Ramiro Avidad Castaneda
    • 1
  1. 1.Department of Analytical ChemistryUniversity of GranadaGranadaSpain

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