Crystal and molecular structure of a new biguanide metal complex, [Cu(AMNH)2]Cl2

  • Bankim C. Das
  • I. Dey
  • G. Biswas
  • R. Banerjee
  • Y. Iitaka
  • A. Banerjee
Article

Abstract

The crystal structure of C6H16N8O2·CuCl2, a biguanide metal complex, has been determined by X-ray diffraction data using Mo radiation. The compound crystallizes in the monoclinic space groupP21/a, witha=11.074(4),b=12.061(4),c=5.312(3)Å andβ=102.8(1)°.

The structure was solved by direct methods and refined by full-matrix least-squares to a finalR value 0.037 with 1245 unique reflections. The complex molecule is centrosymmetric, with the Cu atom (0.5,0.5,0.5) on a crystallographic center of symmetry. The complex molecule is rhombic planar with a trans configuration.

Keywords

Radiation Reflection Physical Chemistry Crystal Structure Inorganic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Angelo, M., Ortwine, D., Worth, D., Werbel, L. M., and McCall, J. W. (1983)J. Med. Chem. 26, 1258.Google Scholar
  2. Andreetti, G. D., Coghi, L., Nardelli, M., and Sgarabotto, P. (1971)J. Cryst. Mol. Struct. 1, 147.Google Scholar
  3. Banerjee, R. (1992)Indian J. Chem. (communicated).Google Scholar
  4. Bailey, C. L. (1985)Int. Congr. Symp. Ser. R. Soc. Med. 79, 17.Google Scholar
  5. Bespalov, V. G., and Aleksandrov, V. A. (1985)Byull. Eksp. Biol. Med. 100, 73.Google Scholar
  6. Byckowski, J. Z., and Porter, C. W. (1983)Gen. Pharmacol. 14, 615.Google Scholar
  7. Bygbjerg, I. C. (1985)Eur. J. Clin. Pharmacol. 28, 287.Google Scholar
  8. Curd, F. H. S., and Rose, F. L. (1946)J. Chem. Soc. 729.Google Scholar
  9. Coghi, L., Mangia, A., Nardelli, M., and Pelizzi, G. (1969)Ric. Sci. 39, 438.Google Scholar
  10. Coghi, L., Mangia, A., Nardelli, M., Plezzi, G., and Sozzi, L. (1968)Chem. Comm. 23, 1475.Google Scholar
  11. De, A. (1990)J. Cryst. Spectr. Res. 20(3), 279.Google Scholar
  12. Freeman, H. C., Robinson, G., and Schoone, J. C. (1964)Acta Cryst. 17, 719.Google Scholar
  13. Holian, B. L., and Marsh, R. E. (1970)Acta Cryst. B 26, 1049.Google Scholar
  14. Kashiwagi, S. (1974)Fuknoka Igaku Zasshi. 65, 157.Google Scholar
  15. Kunchur, N. R., and Mathew, M. (1966)Chem. Commun. 86.Google Scholar
  16. Kunchur, N. R. (1968)Nature (London),217, 539.Google Scholar
  17. Mathew, M., and Kunchur, N. R. (1970)Acta Cryst. B 26, 2054.Google Scholar
  18. Nardelli, M. (1983)Comput. Chem. 7, 95.Google Scholar
  19. Pradalier, A., and Casassns, H. (1974)Diabetes 22, 203.Google Scholar
  20. Ray P., and Chakrabarty, K. (1944)J. Indian. Chem. Soc. 21, 47.Google Scholar
  21. Shannon, R. (1970)Acta Cryst. A 32, 751.Google Scholar
  22. Sheldrick, G. M. (1978)SHELX-76. Programs for crystal structure determination. Univ. of Cambridge, England.Google Scholar
  23. Sheldrick, G. M. (1986)SHELXS86. Program for the solution of crystal structures. Univ. of Gottingen, Germany.Google Scholar
  24. Ward, D. L., Caughlan, C. N., and Smith, G. D. (1971)Acta Cryst. B 27, 1541.Google Scholar

Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • Bankim C. Das
    • 1
  • I. Dey
    • 1
  • G. Biswas
    • 1
  • R. Banerjee
    • 2
  • Y. Iitaka
    • 3
  • A. Banerjee
    • 1
  1. 1.Biophysics DepartmentBose InstituteCalcutta-54India
  2. 2.Chemistry DepartmentJadavpur UniversityCalcutta-32India
  3. 3.Faculty of Pharmaceutical SciencesTokyo UniversityTokyoJapan

Personalised recommendations