Infrared spectroscopic study of water in the hydrates of calcium nitroprusside: Ca[Fe(CN)5NO]·nH2O (n=1,4)
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Abstract
The infrared absorption bands due to the water molecules in calcium nitroprusside monohydrate and tetrahydrate were studied using partial deuteration and low-temperature techniques. An assignment of these bands based on the possible hydrogen bonds existing in the crystal lattice is proposed. Additional infrared spectroscopic data on the monohydrate and the anhydrous compound are included.
Keywords
Hydrogen Hydrate Hydrogen Bond Inorganic Chemistry Water Molecule
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© Plenum Publishing Corporation 1984