Crystal and molecular structure of ibogamine: An alkaloid fromStemmadenia galeottiana

  • M. Soriano-García
  • F. Walls
  • A. Rodríguez
  • I. López Celis
Article

DOI: 10.1007/BF01181911

Cite this article as:
Soriano-García, M., Walls, F., Rodríguez, A. et al. Journal of Crystallographic and Spectroscopic Research (1988) 18: 197. doi:10.1007/BF01181911

Abstract

C19H24N2 is orthorhombic,D24-P212121. Unit cell dimensions at 293 K area=10.346(7),b=10.464(3),c=29.083(10)Å,V=3149(4) Å3,Dc=1.18 g cm−3, andZ=8. The structure has been determined from single-crystal data collected with a four-circle diffractometer and refined from 1968 reflections down toR=0.045 andωR=0.047. The structural features determined from chemical and spectroscopic studies are confirmed and extended. There are two crystallographically independent molecules (A and B). In both A and B molecules the indole ring system is planar and attached to a seven-membered nitrogen-containing ring with a distorted-chair conformation. The indole and seven-membered rings lie close to the same plane [dihedral angles are 6.6(5) and 4.1(5)° for the A and B molecules, respectively], while the C(5)-N(6)-C(19)-C(2) atoms of the central axis of theiso-quinuclidine tricyclic structure are almost perpendicular to seven-membered ring [dihedral angles are 84.7(5) and 87.9(5)° for the A and B molecules, respectively]. The A and B molecules in the crystal are packed at normal van der Waals distances.

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • M. Soriano-García
    • 1
  • F. Walls
    • 1
  • A. Rodríguez
    • 1
  • I. López Celis
    • 1
  1. 1.Instituto de Química de la Universidad Nacional Autónoma de MéxicoCoyoacánMéxico, D.F.

Personalised recommendations