Ionic-molecular composition of aqueous sulfuric acid solutions at 25°
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Conclusions
- 1.
Based on the literature data, we calculated the concentrations of the H5O2+ and H3O+ ions, and also of the H3O+·HSO4− ion pairs (or H2SO4·H2O hydrates), in aqueous H2SO4 solutions (ranging from 2.04 to 100% H2SO4).
- 2.
It is postulated that the H3O+ ions can exist only in solutions that contain more than 76% H2SO4, where less than two water molecules correspond to each proton.
Keywords
Hydrate Water Molecule Sulfuric Acid H2SO4 Acid Solution
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Literature cited
- 1.N. G. Zarakhani, N. B. Librovich, and M. I. Vinnik, Zh. Fiz. Khim.,45, 1733 (1971).Google Scholar
- 2.J. C. D. Brand, J. Chem. Soc.,1950, 1002.Google Scholar
- 3.V. D. Maiorov and N. B. Librovich, Zh. Fiz. Khim.,47, 2298 (1973).Google Scholar
- 4.N. B. Librovich, V. D. Maiorov, and V. A. Savel'ev, Dokl. Akad. Nauk SSSR,225, 1358 (1975).Google Scholar
- 5.M. I. Vinnik and N. B. Librovich, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2211.Google Scholar
- 6.N. B. Librovich and M. I. Vinnik, Zh. Fiz. Khim.,50, 150 (1976).Google Scholar
- 7.M. I. Vinnik and N. B. Librovich, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 1480.Google Scholar
- 8.M. I. Vinnik, L. R. Andreeva, and I. M. Medvetskaya, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 540.Google Scholar
- 9.N. B. Librovich and V. D. Maiorov, Dokl. Akad. Nauk SSSR,198, 1371 (1971).Google Scholar
- 10.V. D. Maiorov and N. B. Kobrovich, Zh. Fiz. Khim.,49, 2819 (1975).Google Scholar
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© Plenum Publishing Corporation 1977