Isomerization of some diene hydrocarbons in the presence of calcium amide

  • I. V. Gostunskaya
  • N. I. Tyun'kina
  • B. A. Kazanskii
Brief Communications


  1. 1.

    The relative rates of isomerlzation of 1,5-hexadiene, 2-methyl-1,5-hexadiene, and 2,5-dimethyl-1,5-hexadiene in presence of calcium amide are very close in value.

  2. 2.

    The results confirm the proposed mechanism of the displacement of double bonds in presence of metal amides.



Calcium Amide Hydrocarbon Double Bond Diene 
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Literature cited

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    I. V. Gostunskaya and B. A. Kazanskii, Zhur. Obshchei Khim25, 1995 (1955).Google Scholar
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    I. V. Gostunskaya, N. I. Tyun'kina, and B. A. Kazanskii, Doklady Akad. Nauk SSSR108, 473 (1956).Google Scholar
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    A. Henne and A. Turk, J. Amer. Chem. Soc.64, 826 (1942).Google Scholar
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    A. I. Shatenshtein, Uspekhi Khim.24, 377 (1955).Google Scholar

Copyright information

© Consultants Bureau, Inc. 1960

Authors and Affiliations

  • I. V. Gostunskaya
    • 1
  • N. I. Tyun'kina
    • 1
  • B. A. Kazanskii
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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