Chemistry of acetals
Communication 22. Condensation of 2,4-pentanedione and 1.3-cyclohexanedione with acetals
Organic and Biological Chemistry
Received:
Conclusions
- 1.
The condensation of the acetals of some saturated and acetylenic aldehydes with 2,4-pentanedione and 1,3-cyclohexanedione was studied.
- 2.
Views are expressed concerning the possible mechanism of the formation of enol ethers ofβ-carbonyl compounds in the condensation of compounds containing a mobile hydrogen atom with acetals.
Keywords
Hydrogen Acetal Ether Aldehyde Hydrogen Atom
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited
- 1.S. S. Yufit, Zh. A. Krasnaya, T. S. Levchenko, and V. F. Kucherov, Izv. AN SSSR, Ser. khim.,1967, 132.Google Scholar
- 2.J. Klein and E. D. Bergmann, J. Amer. Chem. Soc.,79, 3452 (1957).Google Scholar
- 3.S. Sugden, J. Chem. Soc.,1929, 329.Google Scholar
- 4.J. H. Brown, Jr. and N. B. Lorette, U. S. Patent 2,978,469 (1961); Chem. Abstrs.,55, 1642e (1961).Google Scholar
- 5.M. R. Kulibekov and A. K. Gorban', Zh. obshch. khimii,33, 3587 (1963).Google Scholar
- 6.S. S. Yufit and V. F. Kucherov, Izv. AN SSSR, Otd. khim. n.,1960, 1658.Google Scholar
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