Reactivity of nitrocompounds

Communication 6. Mechanism of the hydration of α-nitrocrotonic ester
  • V. M. Belikov
  • Yu. N. Belokon'
Physical Chemistry
Received:

Conclusions

  1. 1.

    As a result of an investigation of the hydration ofα-nitrocrotonic ester in water at pH < 3.0, it was shown that the step limiting the rate of the process is recombination of the intermediate C -anion ofα-nitro-β-hydroxybutyric ester.

     
  2. 2.

    The decomposition ofα-nitrocrotonic ester at pH>4.0 leads to the production of nitroacetic ester and acetaldehyde. The formation of an intermediate C-anion ofα-nitro-β-hydroxybutyric acid was demonstrated in this case.

     

Keywords

Acetaldehyde Ester Hydration Recombination Nitrocompounds 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • V. M. Belikov
    • 1
  • Yu. N. Belokon'
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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